Co(II), Ni(II) and Cu(II) complexes og 1,4-DI-(1-hydroxyimino-2-phenyl-2-oxo-ethylamino)benzene - Synthesis, characterization and thermal studies

Abstract

The ligand has been prepared from omega-chloroisonitrosoacetophenone and 1,4-phenylenediamine in the presence of NaHCO3. The ligand have a C=O group and an -NH-R group adjacent to the oxime group. The Ni(II), Cu(II) and Co(II) complexes of the synthesized ligand were prepared and their structures were identified using FTIR, UV-Vis spectral data, elemental analysis, thermal analysis and magnetic moment measurements. The metal-ligand ratios were found to be 3:2. The ligands were found to coordinate to the metal ions via the oxime nitrogen, oxime oxygen, one of the carbonyl group and amide nitrogen atoms. Thermal analyses data reveals that the water in the complexes was found to be non-coordinated to the metal ions. In the trinuclear structures, the metals have the tetrahedral environments.