dc.contributor.author | Yeşilel, Orkan Zafer | |
dc.contributor.author | Akdag, Kamber | |
dc.contributor.author | Pasaoglu, Humeyra | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.date.accessioned | 2020-06-21T15:20:10Z | |
dc.date.available | 2020-06-21T15:20:10Z | |
dc.date.issued | 2007 | |
dc.identifier.issn | 0932-0776 | |
dc.identifier.issn | 1865-7117 | |
dc.identifier.uri | https://doi.org/10.1515/znb-2007-0610 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/19968 | |
dc.description | YESILEL, Okan Zafer/0000-0002-2284-1578 | en_US |
dc.description | WOS: 000248068300010 | en_US |
dc.description.abstract | The mer-bis(2-aminothiazole)diaqua-orotato-nickel(II) complex, mer-[Ni(HOr)(H2O)(2)(ata)(2)] (1), was synthesized and characterized by spectral (IR and UV/vis) and thermal studies. In addition, the crystal structure of the complex was determined by single crystal X-ray diffraction. The complex crystallizes in the triclinic system, space group P1. The orotate ligand is coordinated to the nickel(II) atom through a nitrogen atom of the pyrimidine ring and an oxygen atom of the carboxylate group as a bidentate dianion. The coordination of the Ni(II) ion is extended to six by the two 2-aminothiazoles (ata) and two water molecules. The thermal decomposition has been studied in a static air atmosphere. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Walter De Gruyter Gmbh | en_US |
dc.relation.isversionof | 10.1515/znb-2007-0610 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | orotato complex | en_US |
dc.subject | vitamin B13 complex | en_US |
dc.subject | 2-aminothiazole | en_US |
dc.title | Synthesis and spectral, thermal and structural characterization of a vitamin B13 complex of nickel(II) with 2-aminothiazole, mer-[Ni(HOr)(H2O)(2)(ata)(2)] | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 62 | en_US |
dc.identifier.issue | 6 | en_US |
dc.identifier.startpage | 818 | en_US |
dc.identifier.endpage | 822 | en_US |
dc.relation.journal | Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |