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dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorYeşilel, Orkan Zafer
dc.contributor.authorKavlak, Ikan
dc.contributor.authorBüyükgüngör, Orhan
dc.date.accessioned2020-06-21T15:12:49Z
dc.date.available2020-06-21T15:12:49Z
dc.date.issued2008
dc.identifier.issn1040-0400
dc.identifier.issn1572-9001
dc.identifier.urihttps://doi.org/10.1007/s11224-008-9354-3
dc.identifier.urihttps://hdl.handle.net/20.500.12712/19104
dc.descriptionYESILEL, Okan Zafer/0000-0002-2284-1578en_US
dc.descriptionWOS: 000261037700003en_US
dc.description.abstractPolymeric tetracyanonickelate complexes of the type [M(H2O)(2mpz)Ni(mu-CN)(4)] (n) (2mpz = 2-methylpyrazine, M = Mn(II) (1) or Cd(II) (2)) have been prepared and characterized by FT-IR, Raman spectroscopy, thermal, and elemental analyses. The crystal structure of supramolecular [Cd(H2O)(2mpz)Ni(CN)(4)] (n) complex has been determined by X-ray single crystal diffraction. It crystallizes in the orthorhombic system, space group Pnma. The structure consists of corrugated and cyanide-bridged polymeric two-dimensional networks. In the Hofmann-type complexes, the coordination environment of the M(II) ions can be described as distorted octahedral geometry, whereas around the Ni(II) center has square planar geometry. The spectral features suggest that the 2mpz is coordinated to metal ions of the adjacent layers of [M-Ni(CN)(4)] (n) as monodentate ligand. The thermal decomposition of these complexes takes place in three stages: (i) dehydration, (ii) decomposition of the 2-methylpyrazine ligands, and (iii) release of the CN groups and burning of organic residue.en_US
dc.language.isoengen_US
dc.publisherSpringer/Plenum Publishersen_US
dc.relation.isversionof10.1007/s11224-008-9354-3en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyano-bridging complexesen_US
dc.subjectTetracyanonickelateen_US
dc.subject2-Methylpyrazine complexesen_US
dc.subjectVibrational spectraen_US
dc.titleSyntheses, spectral and thermal analyses of heteronuclear aqua(2-methylpyrazine)metal(II) complexes with tetracyanonickelate ion and crystal structure of supramolecular [Cd(H2O)(2mpz)Ni(mu-CN)(4)] (n) complexen_US
dc.typearticleen_US
dc.contributor.departmentOMÜen_US
dc.identifier.volume19en_US
dc.identifier.issue6en_US
dc.identifier.startpage879en_US
dc.identifier.endpage888en_US
dc.relation.journalStructural Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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