dc.contributor.author | Tas, Murat | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.date.accessioned | 2020-06-21T15:06:38Z | |
dc.date.available | 2020-06-21T15:06:38Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0253-4134 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/18665 | |
dc.description | TAS, MURAT/0000-0002-2879-6501 | en_US |
dc.description | WOS: 000268244200003 | en_US |
dc.description.abstract | The reaction of aqueous cobaltous nitrate hexahydrate with the anion of succinimide (sucH) in the presence of excess ethylenediamine (en) in air results in the formation of a dinuclear complex mu-peroxo-bis[bis(ethylenediamine)succinimidato-cobalt(III)] dinitrate dihydrate, 1, in good yield. Compound 1 was characterized by elemental analysis, IR, visible spectra and magnetic susceptibility studies. The explosive nature of [Co(en)(2)(suc)(mu-O(2))Co(en)(2)(suc)](NO(3))(2)center dot 2H(2)O, 1, precluded its thermal characterization. Compound 1 crystallises in the monoclinic space group P2(1)/c and a half of the molecule, constitutes its asymmetric unit. In the centrosymmetric dinuclear complex 1, two Co(III) centres, are linked by a planar peroxide bridge. Each cobalt atom is surrounded by four nitrogen atoms of ethylenediamine ligands, a nitrogen atom of succinimidato anion and an oxygen atom of peroxo bridge resulting in a slightly distorted {CoN(5)O} octahedron. Due to steric hindrance between the two Co(III) centres, the peroxide bridge is planar with a Co-O-O-Co torsion angle of 180 degrees. The dinuclear complex cation, the nitrate anion and the lattice water are involved in three varieties of H-bonding interactions namely N-H center dot center dot center dot O, O-H center dot center dot center dot O and C-H center dot center dot center dot O. | en_US |
dc.description.sponsorship | TUBITAK (The Scientific and Technical Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [106T195] | en_US |
dc.description.sponsorship | This study was supported in part by a grant from TUBITAK (The Scientific and Technical Research Council of Turkey) (TBAG/HD 106T195 to Murat TA$). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Indian Acad Sciences | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Ethylenediamine | en_US |
dc.subject | succinimide | en_US |
dc.subject | succinimidato | en_US |
dc.subject | peroxo bridge | en_US |
dc.subject | dinuclear | en_US |
dc.subject | H-bonding | en_US |
dc.title | Synthesis and structural characterization of a novel peroxo bridged dinuclear cobalt(III) complex of succinimide showing three varieties of hydrogen bonding interactions | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 121 | en_US |
dc.identifier.issue | 3 | en_US |
dc.identifier.startpage | 267 | en_US |
dc.identifier.endpage | 273 | en_US |
dc.relation.journal | Journal of Chemical Sciences | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |