| dc.contributor.author | Sari, Musa | |
| dc.contributor.author | Poyraz, Mehmet | |
| dc.contributor.author | Büyükgüngör, Orhan | |
| dc.date.accessioned | 2020-06-21T15:06:14Z | |
| dc.date.available | 2020-06-21T15:06:14Z | |
| dc.date.issued | 2009 | |
| dc.identifier.issn | 1074-1542 | |
| dc.identifier.uri | https://doi.org/10.1007/s10870-009-9527-y | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/18522 | |
| dc.description | WOS: 000267031200002 | en_US |
| dc.description.abstract | The complex, [Mn6O2(OOCCMe3)(10)(HOO-CCMe3)(3)(py)], has a hexanuclear structure with a Mn6O2 core. This complex crystallizes in the monoclinic space group P2(1)/n with a = 17.757(5) angstrom, b = 27.413(5) angstrom, c = 22.348(5) angstrom, beta = 90.233(5)degrees, V = 9,040(4) angstrom(3) and Z = 4. It contains a [Mn6O2](10+) core that can be described as two edge-sharing Mn-4 tetrahedra at the centre of each of which tetrahedron lies a mu(4)-O2- ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. Mn-4 exhibits butterfly arrangement with both mu(4)-O atoms on the same side of the molecule. The complex is mixed-valence ((Mn4Mn2III)-Mn-II), and the Mn-III centers are assigned as the two central metal ions bridged by two O2- ions. | en_US |
| dc.description.sponsorship | Gazi University Scientific Research UnitGazi University [BAP-04/2004-12] | en_US |
| dc.description.sponsorship | The authors wish to acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for use of the Stoe IPDS-2 diffractometer purchased under grant F. 279 of the University Research Fund and also thank Gazi University Scientific Research Unit (BAP-04/2004-12) for financial support for this study. | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Springer/Plenum Publishers | en_US |
| dc.relation.isversionof | 10.1007/s10870-009-9527-y | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Mixed-valence | en_US |
| dc.subject | Hexanuclear structure | en_US |
| dc.subject | Clusters | en_US |
| dc.subject | Crystal structure | en_US |
| dc.title | Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis(mu(2)-pivalato)-tetrakis(mu(3)-pivalato)-mono(pyridine)-tris(pivalic acid)-bis(mu(4)-oxo)dimanganese(III) tetramanganase(II) | en_US |
| dc.type | article | en_US |
| dc.contributor.department | OMÜ | en_US |
| dc.identifier.volume | 39 | en_US |
| dc.identifier.issue | 8 | en_US |
| dc.identifier.startpage | 549 | en_US |
| dc.identifier.endpage | 552 | en_US |
| dc.relation.journal | Journal of Chemical Crystallography | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
