| dc.contributor.author | Guney, Emel | |
| dc.contributor.author | Yılmaz, Veysel T. | |
| dc.contributor.author | Büyükgüngör, Orhan | |
| dc.date.accessioned | 2020-06-21T14:48:53Z | |
| dc.date.available | 2020-06-21T14:48:53Z | |
| dc.date.issued | 2010 | |
| dc.identifier.issn | 1387-7003 | |
| dc.identifier.issn | 1879-0259 | |
| dc.identifier.uri | https://doi.org/10.1016/j.inoche.2010.02.005 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/17987 | |
| dc.description | Yilmaz, Veysel/0000-0002-2849-3332 | en_US |
| dc.description | WOS: 000276751000029 | en_US |
| dc.description.abstract | A three-dimensional silver(I)-saccharinato (sac) coordination polymer [Ag-2(mu-Sac)21,, has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. The silver(I) ions are doubly bridged by the imino N and carbonyl O atoms of two sac ligands, leading to a dimer [Ag-2(mu-sac)(2)] with a very short Ag-Ag contact of 2.8622(6) angstrom. The dimeric units are linked by unique Ag-C-sac (eta(1)) bonds into two-dimensional ladder-like layers, which are further assembled into a three-dimensional network by weak Ag ...O(sulphonyl) and pi(sac) ... pi(sac) interactions. Complex 1 is the first example of a polymeric network involving the eta(1) Ag-C bonds. In addition to the new coordination mode of sac, the IR spectrum and thermal properties of the complex were discussed. (C) 2010 Elsevier B.V. All rights reserved. | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Elsevier | en_US |
| dc.relation.isversionof | 10.1016/j.inoche.2010.02.005 | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Saccharinate | en_US |
| dc.subject | Silver(I) | en_US |
| dc.subject | Coordination polymer | en_US |
| dc.subject | Ag-C bond | en_US |
| dc.subject | Ag ... Ag interaction | en_US |
| dc.title | A three-dimensional silver(I) coordination polymer involving a new bridging mode of saccharinate | en_US |
| dc.type | article | en_US |
| dc.contributor.department | OMÜ | en_US |
| dc.identifier.volume | 13 | en_US |
| dc.identifier.issue | 4 | en_US |
| dc.identifier.startpage | 563 | en_US |
| dc.identifier.endpage | 567 | en_US |
| dc.relation.journal | Inorganic Chemistry Communications | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
