dc.contributor.author | Erer, Hakan | |
dc.contributor.author | Yeşilel, Orkan Zafer | |
dc.contributor.author | Dege, Necmi | |
dc.contributor.author | Alpaslan, Yelda Bingoel | |
dc.date.accessioned | 2020-06-21T14:48:10Z | |
dc.date.available | 2020-06-21T14:48:10Z | |
dc.date.issued | 2010 | |
dc.identifier.issn | 1574-1443 | |
dc.identifier.issn | 1574-1451 | |
dc.identifier.uri | https://doi.org/10.1007/s10904-010-9350-0 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/17899 | |
dc.description | YESILEL, Okan Zafer/0000-0002-2284-1578; Dege, Necmi/0000-0003-0660-4721; | en_US |
dc.description | WOS: 000277284600028 | en_US |
dc.description.abstract | A novel 1D coordination polymer {[Ni(mu-sq)(H2O)(2)(tmen)]center dot H2O}(n) (H(2)sq = squaric acid and tmen = N,N,N',N' -tetramethylethylenediamine) has been synthesized and structurally characterized by X-ray crystallography. The spectral (IR and UV-vis.) and magnetic susceptibility are reported. The structure of the complex consists of the bidentate tmen ligand bound to Ni(II) center and a bridging squarate in the 1,3-bonding mode. The distorted octahedral geometry of Ni(II) is completed by two aqua ligands. The structure contains chains of squarato-O (1) ,O (3) -bridged polynuclear nickel(II) units held together by intermolecular hydrogen bonds interactions between water molecules and oxygen atoms of squarate ligand forming a novel R6 motif. | en_US |
dc.description.sponsorship | University Research Fund [F.279] | en_US |
dc.description.sponsorship | The authors acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased under grant F.279 of the University Research Fund). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Springer | en_US |
dc.relation.isversionof | 10.1007/s10904-010-9350-0 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Squarate complex | en_US |
dc.subject | N,N,N ',N '-Tetramethylethylenediamine complex | en_US |
dc.subject | Coordination polymer, Ni(II) complex | en_US |
dc.title | One Dimensional Coordination Polymer of Nickel(II)-Squarate with N,N,N',N'-tetramethylethylenediamine, {[Ni(mu-sq)(H2O)(2)(tmen)]center dot H2O}(n) | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 20 | en_US |
dc.identifier.issue | 2 | en_US |
dc.identifier.startpage | 411 | en_US |
dc.identifier.endpage | 415 | en_US |
dc.relation.journal | Journal of Inorganic and Organometallic Polymers and Materials | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |