dc.contributor.author | Caglar, Sema | |
dc.contributor.author | Heren, Zerrin | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.date.accessioned | 2020-06-21T14:46:24Z | |
dc.date.available | 2020-06-21T14:46:24Z | |
dc.date.issued | 2011 | |
dc.identifier.issn | 0095-8972 | |
dc.identifier.issn | 1029-0389 | |
dc.identifier.uri | https://doi.org/10.1080/00958972.2011.605880 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/17534 | |
dc.description | WOS: 000299465800013 | en_US |
dc.description.abstract | Four 2-benzoylbenzoate (bba) complexes, [Co(bba)(2)(H2O)(2)(3-pic)(2)] (1), [Ni(bba)(2)(H2O)(2)(3-pic)(2)] (2), [Cu(bba)(2)(3-pic)(2)] (3), and [Hg(bba)(2)(3-pic)(2)] (4), have been synthesized and characterized by IR spectra, thermal (TG, DTG, and DTA) analysis, and single crystal X-ray diffraction. All the complexes consist of neutral monomeric units with 1 and 2 crystallizing in the orthorhombic (P n a 2(1)), 3 in triclinic (P (1) over bar), and 4 in monoclinic (P2(1)/c) crystal systems. The metal(II) ions exhibit distorted octahedral coordination for 1, 2, and 3 and mercury(II) exhibits distorted trigonal prism coordination. In 1 and 2, bba is monodentate, whereas in 3 and 4 bba is bidentate. 3-Picoline (3-pic) is a classical N-monodentate ligand. Bba are coordinated to metal(II) with carboxylates and IR spectra of all complexes display characteristic absorptions of carboxylate {v(OCO)(asym) and v(OCO)(sym)}. Thermogravimetric (TG) analyses show that 1 and 2 are thermally stable (T-decomp.>60 degrees C) and 3 and 4 are thermally stable (T-decomp.>120 degrees C). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis Ltd | en_US |
dc.relation.isversionof | 10.1080/00958972.2011.605880 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 2-Benzoylbenzoic acid | en_US |
dc.subject | 3-Picoline | en_US |
dc.subject | Metal(II) complexes | en_US |
dc.subject | Crystal structure | en_US |
dc.title | Synthesis, crystal structures, thermal, and spectroscopic properties of four new metal(II) (M = Co, Ni, Cu, Hg) complexes of 2-benzoylbenzoate with 3-picoline | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 64 | en_US |
dc.identifier.issue | 15 | en_US |
dc.identifier.startpage | 2706 | en_US |
dc.identifier.endpage | 2717 | en_US |
dc.relation.journal | Journal of Coordination Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |