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dc.contributor.authorYeşilel, Orkan Zafer
dc.contributor.authorErer, Hakan
dc.contributor.authorBüyükgüngör, Orhan
dc.date.accessioned2020-06-21T14:42:15Z
dc.date.available2020-06-21T14:42:15Z
dc.date.issued2011
dc.identifier.issn1466-8033
dc.identifier.urihttps://doi.org/10.1039/c0ce00308e
dc.identifier.urihttps://hdl.handle.net/20.500.12712/17499
dc.descriptionYESILEL, Okan Zafer/0000-0002-2284-1578en_US
dc.descriptionWOS: 000287458500013en_US
dc.description.abstractThree novel cadmium(II) complexes containing orotate ligand have been synthesized under different pH and characterized by X-ray crystallography, IR spectroscopy and thermal analyses measurements. In the complexes, the orotate ligand exhibits three different coordination modes. In [Cd-2(mu-HOr)(2)(H2O)(4)(NH3)(2)]center dot 2H(2)O (1), the orotate acts as a tridentate ligand, showing unprecedented coordination mode. The (NH4)(2)[Cd-3(mu-HOr)(2)(HOr)(2)(H2O)(8)]center dot 4H(2)O (2) is constructed from orotate acting as both bidentate and tridentate bridging ligands. The Cd1 and Cd2 ions have two different coordination environments with four HOr, eight aqua ligands. Furthermore, 2 exhibits the novel 2D metal-water cluster layers. The (Hcha)(4)[Cd(HOr)(2)(H2O)(cha)][Cd(HOr)(2)(H2O)(2)]center dot H2O (3) (cha cyclohexylamine, H(3)Or = orotic acid) consists of discrete cis and trans anionic complexes. The cha molecules exhibit chemically different functions by coordinating to Cd(II) ion in one form and being protonated and acting as counter-ions in other form. In the complexes, the supramolecular networks are constructed by novel N-H center dot center dot center dot O strong hydrogen bonds to form DA : AD motif, C=O center dot center dot center dot pi and pi center dot center dot center dot pi interactions.en_US
dc.description.sponsorshipEskisehir Osmangazi UniversityEskisehir Osmangazi University [200819042]en_US
dc.description.sponsorshipThis work was supported by the Eskisehir Osmangazi University by project no. 200819042.en_US
dc.language.isoengen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.isversionof10.1039/c0ce00308een_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleSupramolecular architectures of cadmium(II)-orotate complexes containing water clustersen_US
dc.typearticleen_US
dc.contributor.departmentOMÜen_US
dc.identifier.volume13en_US
dc.identifier.issue5en_US
dc.identifier.startpage1339en_US
dc.identifier.endpage1349en_US
dc.relation.journalCrystengcommen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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