dc.contributor.author | Sema, Caglar | |
dc.contributor.author | Serkan, Demir | |
dc.date.accessioned | 2020-06-21T14:28:19Z | |
dc.date.available | 2020-06-21T14:28:19Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1553-3174 | |
dc.identifier.issn | 1553-3182 | |
dc.identifier.uri | https://doi.org/10.1080/15533174.2012.684263 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/16712 | |
dc.description | WOS: 000313950100019 | en_US |
dc.description.abstract | Two mixed ligand complexes of copper(II)-2-benzoylbenzoate (bba) with pyridazine and 4-picoline, namely bis(2-benzoylben- zoate)di(pyridazine)copper(II) 1 and bis(2-benzoylbenzoate)bis(4-picoline)copper(II) 2, have been synthesized and characterized by X-ray crystallography. Complexes 1 and 2 crystallize in the monoclinic P21/c space groups. The calculated frequency shifts have shown that the participation of carboxylate groups in coordination to the metal centers in monodentate fashion (?(OCO) > 200 cm-1). The structural features of the complexes have been further studied by DFT/X3LYP extended hybrid functional. The thermal behavior of the complexes was studied by means of simultaneous thermogravimetry, differental thermogravimetry, and differential thermal analysis methods in a static air atmosphere. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis Inc | en_US |
dc.relation.isversionof | 10.1080/15533174.2012.684263 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 2-benzoylbenzoate | en_US |
dc.subject | copper(II) complex | en_US |
dc.subject | crystal structure | en_US |
dc.subject | DFT | en_US |
dc.subject | X3LYP | en_US |
dc.title | A Crystallographic, Spectroscopic, Thermal, and DFT Investigation of Mixed Ligand Cu(II) Complexes of 2-benzoylbenzoate | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 42 | en_US |
dc.identifier.issue | 10 | en_US |
dc.identifier.startpage | 1449 | en_US |
dc.identifier.endpage | 1458 | en_US |
dc.relation.journal | Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |