dc.contributor.author | Sayin, Elvan | |
dc.contributor.author | Kurkcuoglu, Gunes Suheyla | |
dc.contributor.author | Yeşilel, Orkan Zafer | |
dc.contributor.author | Hokelek, Tuncer | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.date.accessioned | 2020-06-21T13:56:52Z | |
dc.date.available | 2020-06-21T13:56:52Z | |
dc.date.issued | 2014 | |
dc.identifier.issn | 2194-4946 | |
dc.identifier.issn | 2196-7105 | |
dc.identifier.uri | https://doi.org/10.1515/zkri-2014-1756 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/15045 | |
dc.description | Hokelek, Tuncer/0000-0002-8602-4382; YESILEL, Okan Zafer/0000-0002-2284-1578 | en_US |
dc.description | WOS: 000343696900004 | en_US |
dc.description.abstract | Three new cyano complexes, [Cu(hmp)(2)] [Cu(hmpH)(2)Ni(mu-CN)(2)(CN)(2)](2)center dot 4H(2)O (1), [Zn-3(hmp)(2)(hmpH)(4) Ni-2(mu-CN)(6)(CN)(2)]center dot 2H(2)O (2) and [Cd-2(H2O)(2)(hmpH)(2)Ni(mu-CN)(4)Ni(mu-CN)(2)(CN)(2)] (3) (2-pyridinemethanol abbreviated to hmpH), have been synthesized and characterized by elemental analysis, vibrational spectroscopy (FT-IR and Raman), thermal and single-crystal X-ray diffraction analyses. In 1, Cu(II) ions are connected by the tetracyanonickelate(II) anions to form one-dimensional (1D) zig-zag chains. In 2, tetracyanonickelate(II) ions are coordinated to the neighboring three Zn(II) ions to form a one-dimensional double chain structure. In 3, Cd(II) ions are connected by tetrakis-monodentate tetracyanonickelate(II) ions to form a one-dimensional ladder-like chain. Adjacent ladder-like chains are linked by the bis-monodentate tetracyanonickelate(II) ions to generate a 2D network. The 3D supramolecular network of the complexes constructed by intermolecular interactions such as Ni center dot center dot center dot pi, C-H center dot center dot center dot Ni, pi...pi and hydrogen bonding interactions. | en_US |
dc.description.sponsorship | Eskisehir Osmangazi UniversityEskisehir Osmangazi University [201319D14] | en_US |
dc.description.sponsorship | This work was supported by the Research Fund of Eskisehir Osmangazi University. Project number: 201319D14. The authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Walter De Gruyter Gmbh | en_US |
dc.relation.isversionof | 10.1515/zkri-2014-1756 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | cyanide complexes | en_US |
dc.subject | 2-pyridinemethanol complexes | en_US |
dc.subject | tetracyanonickelate(II) complexes | en_US |
dc.subject | C-H center dot center dot center dot Ni interaction | en_US |
dc.subject | Ni center dot center dot center dot pi interaction | en_US |
dc.subject | pi...pi interaction | en_US |
dc.subject | O-H center dot center dot center dot O interaction | en_US |
dc.title | One- and two-dimensional heteropolynuclear complexes with tetracyanonickelate(II) and 2-pyridinemethanol | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 229 | en_US |
dc.identifier.issue | 8 | en_US |
dc.identifier.startpage | 563 | en_US |
dc.identifier.endpage | 572 | en_US |
dc.relation.journal | Zeitschrift Fur Kristallographie-Crystalline Materials | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |