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dc.contributor.authorSayin, Elvan
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorYeşilel, Orkan Zafer
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorBüyükgüngör, Orhan
dc.date.accessioned2020-06-21T13:56:52Z
dc.date.available2020-06-21T13:56:52Z
dc.date.issued2014
dc.identifier.issn2194-4946
dc.identifier.issn2196-7105
dc.identifier.urihttps://doi.org/10.1515/zkri-2014-1756
dc.identifier.urihttps://hdl.handle.net/20.500.12712/15045
dc.descriptionHokelek, Tuncer/0000-0002-8602-4382; YESILEL, Okan Zafer/0000-0002-2284-1578en_US
dc.descriptionWOS: 000343696900004en_US
dc.description.abstractThree new cyano complexes, [Cu(hmp)(2)] [Cu(hmpH)(2)Ni(mu-CN)(2)(CN)(2)](2)center dot 4H(2)O (1), [Zn-3(hmp)(2)(hmpH)(4) Ni-2(mu-CN)(6)(CN)(2)]center dot 2H(2)O (2) and [Cd-2(H2O)(2)(hmpH)(2)Ni(mu-CN)(4)Ni(mu-CN)(2)(CN)(2)] (3) (2-pyridinemethanol abbreviated to hmpH), have been synthesized and characterized by elemental analysis, vibrational spectroscopy (FT-IR and Raman), thermal and single-crystal X-ray diffraction analyses. In 1, Cu(II) ions are connected by the tetracyanonickelate(II) anions to form one-dimensional (1D) zig-zag chains. In 2, tetracyanonickelate(II) ions are coordinated to the neighboring three Zn(II) ions to form a one-dimensional double chain structure. In 3, Cd(II) ions are connected by tetrakis-monodentate tetracyanonickelate(II) ions to form a one-dimensional ladder-like chain. Adjacent ladder-like chains are linked by the bis-monodentate tetracyanonickelate(II) ions to generate a 2D network. The 3D supramolecular network of the complexes constructed by intermolecular interactions such as Ni center dot center dot center dot pi, C-H center dot center dot center dot Ni, pi...pi and hydrogen bonding interactions.en_US
dc.description.sponsorshipEskisehir Osmangazi UniversityEskisehir Osmangazi University [201319D14]en_US
dc.description.sponsorshipThis work was supported by the Research Fund of Eskisehir Osmangazi University. Project number: 201319D14. The authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer.en_US
dc.language.isoengen_US
dc.publisherWalter De Gruyter Gmbhen_US
dc.relation.isversionof10.1515/zkri-2014-1756en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectcyanide complexesen_US
dc.subject2-pyridinemethanol complexesen_US
dc.subjecttetracyanonickelate(II) complexesen_US
dc.subjectC-H center dot center dot center dot Ni interactionen_US
dc.subjectNi center dot center dot center dot pi interactionen_US
dc.subjectpi...pi interactionen_US
dc.subjectO-H center dot center dot center dot O interactionen_US
dc.titleOne- and two-dimensional heteropolynuclear complexes with tetracyanonickelate(II) and 2-pyridinemethanolen_US
dc.typearticleen_US
dc.contributor.departmentOMÜen_US
dc.identifier.volume229en_US
dc.identifier.issue8en_US
dc.identifier.startpage563en_US
dc.identifier.endpage572en_US
dc.relation.journalZeitschrift Fur Kristallographie-Crystalline Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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