dc.contributor.author | Özdemir, Namık | |
dc.contributor.author | Dayan, Osman | |
dc.contributor.author | Yavasoglu, Melek Tercan | |
dc.contributor.author | Cetinkaya, Bekir | |
dc.date.accessioned | 2020-06-21T13:52:43Z | |
dc.date.available | 2020-06-21T13:52:43Z | |
dc.date.issued | 2014 | |
dc.identifier.issn | 1386-1425 | |
dc.identifier.uri | https://doi.org/10.1016/j.saa.2014.04.148 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/14913 | |
dc.description | Ozdemir, Namik/0000-0003-3371-9874; Cetinkaya, Bekir/0000-0002-4551-8650; dayan, osman/0000-0002-0764-1965 | en_US |
dc.description | WOS: 000338810400020 | en_US |
dc.description | PubMed: 24825668 | en_US |
dc.description.abstract | The title molecular salt (2), 2,2 '-(pyridine-2,6-diyl)bis (1H-benzo[d]imidazol-3-ium) 2,4,6-trimethylbenzenesulfonate chloride (C19H15N52+center dot C9H11O3S-.Cl-), was synthesized unexpectedly from the reaction of 2,6-bis(benzimidazol-2-yl)pyridine (1) with 2-mesitylenesulfonyl chloride. Spectroscopic techniques NMR and UV-vis.) were used to characterize compounds 1 and 2. Solid-state structure of compound 2 was identified by X-ray crystallography. Theoretical characterization of the spectroscopic properties of compounds 1 and 2 was achieved using the density functional theory (DFT) method with the 6-311G(d,p) basis set, and the results were checked against the experimental data. Electronic absorption spectra of the compounds have also been obtained. (C) 2014 Elsevier B.V. All rights reserved. | en_US |
dc.description.sponsorship | Scientific and Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [107T808]; University Research Fund [F-279] | en_US |
dc.description.sponsorship | This research has been supported by The Scientific and Technical Research Council of Turkey (TUBITAK) (Project No: 107T808). We wish to thank Prof. Dr. Orhan Buyukgungor for his help with the data collection and acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the STOE IPDS II diffractometer (purchased under Grant No. F-279 of the University Research Fund). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
dc.relation.isversionof | 10.1016/j.saa.2014.04.148 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | FT-IR | en_US |
dc.subject | NMR | en_US |
dc.subject | UV-vis. | en_US |
dc.subject | DFT calculations | en_US |
dc.title | Synthesis and characterization of 2,2 '-(pyridine-2,6-diyl)bis (1H-benzo[d]imidazol-3-ium) 2,4,6-trimethylbenzenesulfonate chloride by experimental and theoretical methods | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 131 | en_US |
dc.identifier.startpage | 145 | en_US |
dc.identifier.endpage | 152 | en_US |
dc.relation.journal | Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |