| dc.contributor.author | Alisir, Sevim Hamamci | |
| dc.contributor.author | Demir, Serkan | |
| dc.contributor.author | Sariboga, Bahtiyar | |
| dc.contributor.author | Büyükgüngör, Orhan | |
| dc.date.accessioned | 2020-06-21T13:51:50Z | |
| dc.date.available | 2020-06-21T13:51:50Z | |
| dc.date.issued | 2015 | |
| dc.identifier.issn | 0095-8972 | |
| dc.identifier.issn | 1029-0389 | |
| dc.identifier.uri | https://doi.org/10.1080/00958972.2014.978307 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/14772 | |
| dc.description | WOS: 000346266500012 | en_US |
| dc.description.abstract | A polymeric silver(I) complex, [Ag-4(-pydc)(2)(-pm)(2)](n) (1) (pydc=pyridine-3,5-dicarboxylate and pm=pyrimidine), has been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis, and single-crystal X-ray diffraction. X-ray crystallographic data of 1 revealed that pydc exhibits two different coordinaton modes that play a key role in the construction of the 3-D crystal network including Ag-carboxylate clusters in which close Ag-Ag distances exist. The magnitudes of close Ag-Ag interactions in second-order energy (E-2) have been revealed by natural bond orbital analysis performed with single point energy calculation using the experimental geometry of 1. Furthermore, the luminescent properties of 1 show strong fluorescence with two emission maxima in the visible region. Also, 1 has antifungal activity on Candida albicans (MIC value, 4gmL(-1)) and good antibacterial activity on micro-organisms (MIC value, 64-256gmL(-1)). | en_US |
| dc.description.sponsorship | Research Fund of Ondokuz Mayis UniversityOndokuz Mayis University [PYO.MUH.1901.11.011]; Sinop UniversitySinop University | en_US |
| dc.description.sponsorship | The authors are grateful to the Research Fund of Ondokuz Mayis University (Project No. PYO.MUH.1901.11.011) and Sinop University for financial support of this work. We also thank Assoc. Prof Okan Zafer Yesilel for his assistance and Fatih Semerci in obtaining the luminescence spectra. | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Taylor & Francis Ltd | en_US |
| dc.relation.isversionof | 10.1080/00958972.2014.978307 | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Silver(I) complex | en_US |
| dc.subject | Pyridine-3 | en_US |
| dc.subject | 5-dicarboxylate | en_US |
| dc.subject | Coordination polymer | en_US |
| dc.subject | Photoluminescent properties | en_US |
| dc.subject | Antimicrobial properties | en_US |
| dc.title | A disparate 3-D silver(I) coordination polymer of pyridine-3,5-dicarboxylate and pyrimidine with strong intermetallic interactions: X-ray crystallography, photoluminescence and antimicrobial activity | en_US |
| dc.type | article | en_US |
| dc.contributor.department | OMÜ | en_US |
| dc.identifier.volume | 68 | en_US |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.startpage | 155 | en_US |
| dc.identifier.endpage | 168 | en_US |
| dc.relation.journal | Journal of Coordination Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
