| dc.contributor.author | Dayan, Osman | |
| dc.contributor.author | Demirmen, Selin | |
| dc.contributor.author | Özdemir, Namık | |
| dc.date.accessioned | 2020-06-21T13:51:03Z | |
| dc.date.available | 2020-06-21T13:51:03Z | |
| dc.date.issued | 2015 | |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.uri | https://doi.org/10.1016/j.poly.2014.10.012 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/14560 | |
| dc.description | Ozdemir, Namik/0000-0003-3371-9874; dayan, osman/0000-0002-0764-1965 | en_US |
| dc.description | WOS: 000347582900119 | en_US |
| dc.description.abstract | Six ruthenium(II) complexes ([RuCl2(p-cymene)(L1-6)], SD1-6, (L1-6: bidentate pyridyl-benzimidazole ligands)) were synthesized from [RuCl2(p-cymene)](2) dimer and bidentate pyridyl-benzimidazole ligands. The compounds were characterized by elemental analysis, IR, UV-Vis, NMR and X-ray diffraction. The synthesized Ru(II) complexes (SDI-6) were tested as catalysts for the catalytic transfer hydrogenation (CH) of acetophenone to secondary alcohols in the presence of KOH using 2-propanol as a hydrogen source at 82 degrees C. All complexes were active catalysts for TM of acetophenone with good yields under mild conditions (after 15 min, yields of up to 91%). (C) 2014 Elsevier Ltd. All rights reserved. | en_US |
| dc.description.sponsorship | Canakkale Onsekiz Mart University Scientific Research Projects CommissionCanakkale Onsekiz Mart University [FYL-2013-24]; University Research Fund [F-279] | en_US |
| dc.description.sponsorship | We acknowledge Canakkale Onsekiz Mart University Scientific Research Projects Commission (Project No: FYL-2013-24) for support and the Faculty of Arts and Sciences, Ondokuz Maps University, Turkey, for the use of the STOE IPDS II diffractometer (purchased under grant No. F-279 of the University Research Fund). | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
| dc.relation.isversionof | 10.1016/j.poly.2014.10.012 | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Ru(II) complexes | en_US |
| dc.subject | Transfer hydrogenation | en_US |
| dc.subject | Benzimidazoles | en_US |
| dc.subject | Acetophenone | en_US |
| dc.subject | Pyridines | en_US |
| dc.title | Heteroleptic ruthenium(II) complexes of 2-(2-pyridyl)benzimidazoles: A study of catalytic efficiency towards transfer hydrogenation of acetophenone | en_US |
| dc.type | article | en_US |
| dc.contributor.department | OMÜ | en_US |
| dc.identifier.volume | 85 | en_US |
| dc.identifier.startpage | 926 | en_US |
| dc.identifier.endpage | 932 | en_US |
| dc.relation.journal | Polyhedron | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
