dc.contributor.author | Sezer, Gunes Gunay | |
dc.contributor.author | Yeşilel, Orkan Zafer | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.date.accessioned | 2020-06-21T13:19:14Z | |
dc.date.available | 2020-06-21T13:19:14Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 0022-2860 | |
dc.identifier.issn | 1872-8014 | |
dc.identifier.uri | https://doi.org/10.1016/j.molstruc.2017.02.077 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/12402 | |
dc.description | YESILEL, Okan Zafer/0000-0002-2284-1578 | en_US |
dc.description | WOS: 000398870900060 | en_US |
dc.description.abstract | Two 3D coordination polymers, {[Zn(mu(3)-pzdc)(mu-dpeten)(0.5)]center dot 3H(2)O}(n) (1) and [Zn(mu(3)-pzdc)(mu-dpeten)(0.5)](n) (2) (H(2)pzdc = pyrazine-2,3-dicarboxylic acid and dpeten = 1,2-bis(4-pyridyl)ethylene) have been synthesized by hydrothermal methods and structurally characterized by elemental analysis, IR spectroscopy, single-crystal and powder X-ray diffraction. In complex 1, each pzdc ligand bridges three Zn(II) ions through forming two-dimensional layers. The adjacent 2D layers are further connected by dpeten ligand to generate a novel 3D framework containing one-dimensional large porous channel. It displays a 5 connected bnn hexagonal topology with point symbol {4(6).6(4)}. Although the complex 2 was obtained under the same reaction conditions together with complex 1, it exhibits 3D -> 3D a 2-fold interpenetration network with 6-connected pcu alpha-Po primitive cubic topology with point symbol {4(12).6(3)}. The adjacent three Zn(II) ions are linked by tridentate bridging pzdc ligands to form a 2D layer structure. The 2D layers are further bridged by dpeten ligand to form a 3D pillar-layered network. Moreover, thermal and photoluminescent properties of complexes 1 and 2 have also been studied. (C) 2017 Elsevier B.V. All rights reserved. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [109T201] | en_US |
dc.description.sponsorship | This work has been supported by The Scientific and Technological Research Council of Turkey (Project number: 109T201). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier Science Bv | en_US |
dc.relation.isversionof | 10.1016/j.molstruc.2017.02.077 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Coordination polymers | en_US |
dc.subject | Pyrazine-2,3-dicarboxylate complexes | en_US |
dc.subject | 1,2-bis(4-pyridyl)ethylene complexes | en_US |
dc.title | Two 3D Zinc(II) coordination frameworks constructed from pyrazine-2,3-dicarboxylate and 1,2-bis(4-pyridyl)ethylene | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 1137 | en_US |
dc.identifier.startpage | 562 | en_US |
dc.identifier.endpage | 568 | en_US |
dc.relation.journal | Journal of Molecular Structure | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |