Crystal structure of 4-[(2-hvdroxy-3-methoxybenzyl)amino]benzoic acid hemihydrate
Tarih
2019Yazar
Kamaal, SaimaFaizi, Md Serajul Haque
Ali, Arif
Ahmad, Musheer
Gupta, Mayank
Dege, Necmi
Iskenderov, Turganbay
Üst veri
Tüm öğe kaydını gösterÖzet
In the crystal of the title vanilline derivative, 2C(15)H(15)NO(4)center dot H2O, the secondary amine molecule is accompanied by half equivalent of water. The molecule is non-planar, with torsion angle C-aryl-CH2-NH-C-aryl of -83.9 (2)degrees. In the crystal, the system of O-H center dot center dot center dot O hydrogen bonds, including bridging water molecules residing on crystallographic twofold axes, results in a two-dimensional layered structure. Within the layers, there are also weak N-H center dot center dot center dot pi interactions involving the vanilline benzene ring.