dc.contributor.author | Altiparmak, Elif Avcu | |
dc.contributor.author | Erdemir, Gokce | |
dc.contributor.author | Özdemir, Namık | |
dc.contributor.author | Kuruca, Serap Erdem | |
dc.contributor.author | Bal-Demirci, Tulay | |
dc.date.accessioned | 2020-06-21T12:18:05Z | |
dc.date.available | 2020-06-21T12:18:05Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 1144-0546 | |
dc.identifier.issn | 1369-9261 | |
dc.identifier.uri | https://doi.org/10.1039/c9nj04455h | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/10088 | |
dc.description | Ozdemir, Namik/0000-0003-3371-9874 | en_US |
dc.description | WOS: 000524498200017 | en_US |
dc.description.abstract | A triazole complex of copper(ii) containing ethylenediamine as a coligand was synthesized using salicylaldehydethiosemicarbazone in the presence of CuCl2. Also, a dinuclear copper(ii) complex was synthesized using the same reagents; however, the order of their addition was different. The structures of these two complexes were characterized via elemental analysis, IR, H-1-NMR, and UV-Vis spectroscopy and mass spectrometry (MS). Furthermore, the molecular structures of complexes I and II were determined via single-crystal X-ray structure analysis. The copper(ii) ion has a distorted square-pyramidal geometry in complex I and a distorted square-planar geometry in complex II. Their fragmentation products were investigated in detail by ESI-MS. Finally, the cytotoxic effects of both complexes were evaluated in MDA-MB-231, MCF-7 and 3T3 fibroblast cell lines via the MTT assay and flow cytometry. | en_US |
dc.description.sponsorship | Ondokuz Mays UniversityOndokuz Mayis University [PYO.FEN.1906.19.001] | en_US |
dc.description.sponsorship | This study was supported by Ondokuz Mays University (Project No: PYO.FEN.1906.19.001). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Royal Soc Chemistry | en_US |
dc.relation.isversionof | 10.1039/c9nj04455h | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.title | Cu(ii) salen and 1,2,4-triazole complexes from thiosemicarbazone: synthesis, physicochemical and structural properties and cytotoxic activities | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 44 | en_US |
dc.identifier.issue | 14 | en_US |
dc.identifier.startpage | 5333 | en_US |
dc.identifier.endpage | 5342 | en_US |
dc.relation.journal | New Journal of Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |