Yazar "Gunay, M. Emin" için listeleme
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Crystallographic and conformational analysis of 1,3-bis(2,4-dimethoxyphenyl)imidazolidine-2-thione
Karabiyik, Hasan; Gunay, M. Emin; Aygun, Muhittin; Cetinkaya, Bekir; Kazak, Canan (Springer/Plenum Publishers, 2006)The molecular and crystal structures of the title compound, C19H22N2O4S, were determined by single crystal X-ray diffraction technique. The title compound crystallizes in space group F d d 2, with a = 30.785(3) angstrom, ... -
The influence of moisture on deprotonation mode of imidazolinium chlorides with palladacycle acetate dimer
Gunay, M. Emin; Özdemir, Namık; Ulusoy, Mahmut; Ucak, Melih; Dinçer, Muharrem; Cetinkaya, Bekir (Elsevier Science Sa, 2009)Deprotonation of 1,3-diorganyl imidazolinium salts, 1, with N,C-type palladacyclic acetate dimer 2 afforded novel NHC coordinated complexes 3 along with ring opening hydrolysis products 4, which may coordinate to palladium ... -
New (kappa(2)-C,N)-palladacyclic complexes with benzimidazol-2-ylidene ligand: Synthesis, crystal structures and characterization
Gunay, M. Emin; Gumuesada, Rukiye; Özdemir, Namık; Dinçer, Muharrem; Cetinkaya, Bekir (Elsevier Science Bv, 2009)Reaction of unsymmetrical benzimidazolium bromides (1) with Ag2O and subsequent transmetallation with chloro-bridged dinuclear palladacycle, [Pd(dmba)(mu-Cl](2) (dmba: N,N-dimethylbenzylamine) afforded benzannulated ... -
Preparation and crystal structure of binuclear chloro{6-[[chloro(triphenylphosphine)platinum](mesitylimino)methyl]pyridin-2-yl}bis(triphenylphosphine)platinum(II)
Gunay, M. Emin; Dayan, Osman; Gokce, Aytac Gurhan; Aygun, Muhittin; Cetinkaya, Bekir; Büyükgüngör, Orhan (Pergamon-Elsevier Science Ltd, 2008)Treatment of N,N'-bis(mesityl)pyridine-2,6-carboxyimidoyldichloride, 1, in toluene solution with [Pt(PPh3)(4)] at 100 degrees C afforded a novel platinacyclic compound, 3, in 63% yield, instead of the expected compound 2. ... -
The synthesis and structural characterization of a N-heterocyclic carbene-substituted palladacycle
Gokce, Aytac Guerhan; Gunay, M. Emin; Aygun, Muhittin; Cetinkaya, Bekir; Büyükgüngör, Orhan (Taylor & Francis Ltd, 2007)Reaction of {[Pd(dmba)(mu-Cl)](2)} (dmba=(CH3)(2)NCH2C6H4) with ail ill situ generated N-heterocyclic carbene (NHC=1,3-dimesitylimidazolidin-2-ylidene) afforded crystals containing [chloro-(1,3-dimesitylimidazolidin-2-yl ... -
Synthesis, characterization and catalytic activity of Pd( II) complexes with N-allyl functionalized imidazol-2-ylidenes in Suzuki-Miyaura reaction
Gumusada, Rukiye; Özdemir, Namık; Gunay, M. Emin; Dinçer, Muharrem; Soylu, Mustafa Serkan; Cetinkaya, Bekir (Wiley, 2014)A series of Pd-N-heterocyclic carbene (Pd-NHC) complexes were synthesized and characterized by elemental analysis and spectroscopic methods. In addition, the molecular structures of 3c and 4c were determined by X-ray ... -
Synthesis, Spectroscopy, X-ray Crystallography, and DFT Studies of Dichlorobis[1-(allyl)-1H-imidazole-kappa N-3]copper(II)
Yildirim, Ilkay; Firinci, Rukiye; Gunay, M. Emin; Özdemir, Namık (Maik Nauka/Interperiodica/Springer, 2019)The synthesis and characterization of Cu(II) complex bearing N-allylimidazole as ligand have been described and studied by elemental analyses and spectroscopic (FT-IR, UV-Vis) measurements. Molecular structure of Cu(II)-N-allyl ... -
Synthesis, structural, spectroscopic and DFT study on a palladium(II)-N-heterocyclic carbene complex
Firinci, Rukiye; Gunay, M. Emin; Özdemir, Namık; Dinçer, Muharrem (Elsevier Science Bv, 2017)A new palladium complex with N-heterocyclic carbene (NHC) and phosphine ligands was prepared and fully characterized by H-1 NMR, C-13 NMR and P-31 NMR spectroscopies, IR spectroscopy, and X-ray crystallography. The solid-state ... -
Synthesis, X-ray structures, and catalytic activities of (kappa(2)-C,N)-palladacycles bearing imidazol-2-ylidenes
Gunay, M. Emin; Gumusada, Rukiye; Özdemir, Namık; Dinçer, Muharrem; Cetinkaya, Bekir (Elsevier Science Sa, 2009)Quaternisation of methylimidazole (1) by methyl substituted benzyl bromides afforded imidazolium salts (2) which were converted to (kappa(2)-C, N)-palladacycles bearing imidazol-2-ylidenes 6 or 7, by either in situ ...
