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Acid-Catalysed Hydrolysis of Some Aromatic Cyclic Sulfamates

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dc.authorscopusid7801686683
dc.authorscopusid6701793097
dc.authorscopusid8059657200
dc.authorscopusid23064820300
dc.contributor.authorBekdemir, Y.
dc.contributor.authorKütük, H.
dc.contributor.authorCelik, S.
dc.contributor.authorTillett, J.G.
dc.date.accessioned2020-06-21T15:48:51Z
dc.date.available2020-06-21T15:48:51Z
dc.date.issued2002
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Bekdemir] Yunus, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Kütük] Halil, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Celik] Sibel, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Tillett] John G., Department of Chemistry and Biological Chemistry, University of Essex, Colchester, Essex, United Kingdomen_US
dc.description.abstractThe acid catalysed hydrolysis of some cyclic sulfamates, X-3-(p-tolylsulfonyl)-1,2,3-benzoxathiazole 2,2-dioxides (1a, X=Me; 1b, X=H; 1c, X=Cl; 1d, X = NO<inf>2</inf>) have been studied in concentrated aqueous sulfuric and perchloric acid solutions. Analysis of the data by the Excess Acidity Method, activation parameters, substituent, solvent deuterium isotope effect and order of the catalytic effects of the acids are all in agreement with an A-1 mechanism in the studied range.en_US
dc.identifier.doi10.1080/10426500210670
dc.identifier.endpage980en_US
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-0036017998
dc.identifier.scopusqualityQ4
dc.identifier.startpage973en_US
dc.identifier.urihttps://doi.org/10.1080/10426500210670
dc.identifier.volume177en_US
dc.identifier.wosWOS:000176889500020
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofPhosphorus Sulfur and Silicon and the Related Elementsen_US
dc.relation.journalPhosphorus Sulfur and Silicon and the Related Elementsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcid-Catalyzed Hydrolysisen_US
dc.subjectBenzoxathiazoleen_US
dc.subjectCyclic Sulfamateen_US
dc.subjectExcess Acidityen_US
dc.titleAcid-Catalysed Hydrolysis of Some Aromatic Cyclic Sulfamatesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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