Publication: EPR of Cu2+ in Cadmium Saccharin [Cd(sac)2(H2O)4]·2H2O and [Cd(sac)2(hydet-en)2] Complexes in Single-Crystal and Powder Forms
| dc.authorscopusid | 55940997400 | |
| dc.authorscopusid | 56251081500 | |
| dc.authorscopusid | 35555793900 | |
| dc.contributor.author | Yerli, Y. | |
| dc.contributor.author | Karadaǧ, A. | |
| dc.contributor.author | Köksal, F. | |
| dc.date.accessioned | 2020-06-21T15:48:55Z | |
| dc.date.available | 2020-06-21T15:48:55Z | |
| dc.date.issued | 2002 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Yerli] Yusuf, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Karadaǧ] Ahmet, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Köksal] Fevzi, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey | en_US |
| dc.description.abstract | The electron paramagnetic resonance spectra of Cu2+ in [Cd(sac)<inf>2</inf>(H<inf>2</inf>O)<inf>4</inf>]·2H<inf>2</inf>O and [Cd(sac)<inf>2</inf>(HydEt-en)<inf>2</inf>] (HydEt-en = N-(2-hydroxyethyl)-ethylenediamine) single crystals and powder were examined at room temperature. A detailed study of the spectra of the compounds indicates the replacement of Cd2+ in the host compounds with Cu2+. [Cd(sac)<inf>2</inf>(H<inf>2</inf>O)<inf>4</inf>]·2H<inf>2</inf>O shows the presence of two sites for Cu2+ and [Cd(sac)<inf>2</inf>(HydEt-en)<inf>2</inf>] has a single site. The principal values for the g-tensor and the hyperfine tensor for Cu2+ in the two compounds were obtained. The Cu2+ ion was found to be mostly in the 3d<inf>x2-y2</inf> orbital and the ground-state wavefunction of [Cd(sac)<inf>2</inf>(HydEt-en)<inf>2</inf>] was constructed. | en_US |
| dc.identifier.doi | 10.1007/BF03166182 | |
| dc.identifier.endpage | 49 | en_US |
| dc.identifier.issn | 0937-9347 | |
| dc.identifier.issn | 1613-7507 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.scopus | 2-s2.0-0036425956 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.startpage | 43 | en_US |
| dc.identifier.uri | https://doi.org/10.1007/BF03166182 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/22083 | |
| dc.identifier.volume | 23 | en_US |
| dc.identifier.wos | WOS:000179232900003 | |
| dc.identifier.wosquality | Q4 | |
| dc.language.iso | en | en_US |
| dc.publisher | Springer Wien | en_US |
| dc.relation.ispartof | Applied Magnetic Resonance | en_US |
| dc.relation.journal | Applied Magnetic Resonance | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | EPR of Cu2+ in Cadmium Saccharin [Cd(sac)2(H2O)4]·2H2O and [Cd(sac)2(hydet-en)2] Complexes in Single-Crystal and Powder Forms | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |