Publication: Synthesis, Crystal Structure and Thermal Properties of Copper(II) Orotato Complex with 2,2?-Bipyridine
| dc.contributor.author | Yeşilel O.Z. | |
| dc.contributor.author | Ölmez H. | |
| dc.contributor.author | Içbudak H. | |
| dc.contributor.author | Büyükgüngör, Orhan | |
| dc.date.accessioned | 2020-06-21T09:23:30Z | |
| dc.date.available | 2020-06-21T09:23:30Z | |
| dc.date.issued | 2005 | |
| dc.department | OMÜ | en_US |
| dc.department-temp | Yeşilel, O.Z., Department of Chemistry, Ondokuz Mayis University, 55139 Kurupelit-Samsun, Turkey -- Ölmez, H., Department of Chemistry, Ondokuz Mayis University, 55139 Kurupelit-Samsun, Turkey -- Içbudak, H., Department of Chemistry, Ondokuz Mayis University, 55139 Kurupelit-Samsun, Turkey -- Büyükgüngör, O., Department of Physics, Ondokuz Mayis University, 55139 Kurupelit-Samsun, Turkey -- | en_US |
| dc.description.abstract | A mixed-ligand orotato (HOr) complex of Cu(II) with 2,2?-bipyridine (bipy) was synthesized and characterized by elemental analysis, magnetic susceptibility, UV-vis and FT-IR spectroscopy, TG / DTA techniques and X-ray diffraction analysis. X-Ray diffraction analysis has shown that the square-pyramidal five-coordinate copper atom is chelated by the deprotonated N3 pyrimidine atom and the carboxylate oxygen atom of the bidentate orotato dianion, and to the two nitrogen atoms of the 2,2?-bipyridine molecule. A water molecule is attached above the N3O plane. Thermal analyses showed that the title compound decomposes in two steps over the range 20-1000°C on heating in a static air atmosphere. Intermolecular hydrogen-bonds and ?-ring interactions lead to the formation of a three-dimensional network. © 2005 Verlag der Zeitschrift für Naturforschung. | en_US |
| dc.description.sponsorship | Ondokuz Mayis Ãœniversitesi: F.279 | en_US |
| dc.description.sponsorship | The authors wish to acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the STOE IPDS II diffractometer (purchased under grant F.279 of the University Research Fund). | en_US |
| dc.identifier.endpage | 1142 | en_US |
| dc.identifier.issn | 0932-0776 | |
| dc.identifier.issue | 11 | en_US |
| dc.identifier.startpage | 1138 | en_US |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/3577 | |
| dc.identifier.volume | 60 | en_US |
| dc.language.iso | en | en_US |
| dc.relation.journal | Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | 2,2?-Bipyridine | en_US |
| dc.subject | Orotato Complexes | en_US |
| dc.subject | Spectrothermal Analysis | en_US |
| dc.title | Synthesis, Crystal Structure and Thermal Properties of Copper(II) Orotato Complex with 2,2?-Bipyridine | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |