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Solvent Effects on the Alkaline Hydrolyses of 4-Nitrophenyl N-Aroyl

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dc.authorscopusid6701793097
dc.authorscopusid23064820300
dc.contributor.authorKütük, H.
dc.contributor.authorTillett, J.G.
dc.date.accessioned2020-06-21T15:49:31Z
dc.date.available2020-06-21T15:49:31Z
dc.date.issued2001
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kütük] Halil, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey, Dept. of Biol. and Chemical Sciences, University of Essex, Colchester, Essex, United Kingdom; [Tillett] John G., Dept. of Biol. and Chemical Sciences, University of Essex, Colchester, Essex, United Kingdomen_US
dc.description.abstractSecond-order rate constants have been determined for the alkaline hydrolyses of N-aroyl-p-toluenesulfonimidic esters in aqueous organic solvents. Rate minima were observed with decreasing water concentration in aqueous acetonitrile, dioxane and t-butanol mixtures whereas rates of hydrolysis decrease continuously in MeOH-H<inf>2</inf>O and increase in DMSO-H<inf>2</inf>O. Solvent effects, Arrhenius parameters, and substituent effects are consistent with either an addition-elimination or a concerted S<inf>N</inf>2-type mechanism.en_US
dc.identifier.doi10.1080/10426500108055106
dc.identifier.endpage109en_US
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.scopus2-s2.0-0035649586
dc.identifier.scopusqualityQ4
dc.identifier.startpage95en_US
dc.identifier.urihttps://doi.org/10.1080/10426500108055106
dc.identifier.volume176en_US
dc.identifier.wosWOS:000173018400010
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherTaylor and Francis Ltd.en_US
dc.relation.ispartofPhosphorus Sulfur and Silicon and the Related Elementsen_US
dc.relation.journalPhosphorus Sulfur and Silicon and the Related Elementsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAlkaline Hydrolysisen_US
dc.subjectSolvent Effectsen_US
dc.subjectSulfonimidic Estersen_US
dc.titleSolvent Effects on the Alkaline Hydrolyses of 4-Nitrophenyl N-Aroylen_US
dc.typeArticleen_US
dspace.entity.typePublication

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