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Palladium(II) and Ruthenium(II) Complexes Bearing Arylsulfonate-Based Ligands: Synthesis, Structural Characterization and Catalytic Properties

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dc.authorscopusid56043185500
dc.authorscopusid13805114500
dc.authorscopusid8398877200
dc.contributor.authorKağıt, R.
dc.contributor.authorDayan, O.
dc.contributor.authorÖzdemir, Nutullah
dc.date.accessioned2020-06-21T13:31:55Z
dc.date.available2020-06-21T13:31:55Z
dc.date.issued2016
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kağıt] Reyhan, Department of Chemistry, Çanakkale Onsekiz Mart Üniversitesi, Canakkale, Canakkale, Turkey; [Dayan] Osman, Department of Chemistry, Çanakkale Onsekiz Mart Üniversitesi, Canakkale, Canakkale, Turkey; [Özdemir] Namık, Department of Mathematics and Science Education, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractIn this paper, a series of 4-aminophenyl arylsulfonates (L1–3) and their Schiff bases (L4–6) were synthesized. [Ru(p-cymene)(L1–3)Cl<inf>2</inf>] (K1–3), trans-[Pd(L4-6)<inf>2</inf>] (K4–6), and [Ru(p-cymene)(4-aminophenol)Cl<inf>2</inf>] (K7) type transition metal complexes have been prepared from the reaction of the appropriate metal salt, L1–6 and 4-aminophenol. All compounds characterized with different techniques like C, H, N analysis, NMR, IR and UV–Vis techniques. Solid-state structures of one Ru(II) complex (K1) and one Pd(II) complex (K6) have been determined by single-crystal X-ray diffraction. The complexes K1–7 have been tested as catalysts for the catalytic oxidation of benzyl alcohol to bezaldehyde in the presence of periodic acid (H<inf>5</inf>IO<inf>6</inf>). The results show that Ru(II) complexes are more active catalysts than Pd(II) catalysts for this reaction under worked conditions. © 2016 Elsevier Ltden_US
dc.identifier.doi10.1016/j.poly.2016.06.044
dc.identifier.endpage512en_US
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84978811152
dc.identifier.scopusqualityQ2
dc.identifier.startpage504en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2016.06.044
dc.identifier.urihttps://hdl.handle.net/20.500.12712/13049
dc.identifier.volume117en_US
dc.identifier.wosWOS:000384384500059
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.relation.ispartofPOLYHEDRONen_US
dc.relation.journalPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectArylsulfonate Ligandsen_US
dc.subjectOxidation of Benzyl Alcoholen_US
dc.subjectPd(II) Complexesen_US
dc.subjectRu(II) Complexesen_US
dc.subjectSchiff Bases Ligandsen_US
dc.titlePalladium(II) and Ruthenium(II) Complexes Bearing Arylsulfonate-Based Ligands: Synthesis, Structural Characterization and Catalytic Propertiesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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