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Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano-Bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ-CN)2(CN)2]n

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dc.authorscopusid49863490200
dc.authorscopusid16403949600
dc.authorscopusid25521868500
dc.authorscopusid36039473500
dc.contributor.authorKürkçüoǧlu, G.S.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorKavlak, I.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:12:42Z
dc.date.available2020-06-21T15:12:42Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kürkçüoǧlu] Güneş Süheyla, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Kavlak] İlkan, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe heteronuclear polymeric complex, [Zn(teta)Ni(μ-CN) <inf>2</inf>(CN)<inf>2</inf>]<inf>n</inf> (teta: triethylenetetramine), was synthesized and characterized by elementel analysis, FT-IR spectroscopy, thermal analysis and single crystal X-ray diffraction techniques. The complex crystallizes in the monoclinic system, space group P2<inf>1</inf>/c and in which the ZnII ion exhibits a distorted octahedral coordination by one tetradentate teta ligand and two bridging cyano groups as a trans position, whereas the NiII ion has square planer coordination and is coordinated by four cyano ligands. The decomposition reaction takes places in the temperature range 30-600°C in the static air atmosphere. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.en_US
dc.identifier.doi10.1002/zaac.200800337
dc.identifier.endpage178en_US
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-58149263075
dc.identifier.scopusqualityQ3
dc.identifier.startpage175en_US
dc.identifier.urihttps://doi.org/10.1002/zaac.200800337
dc.identifier.volume635en_US
dc.identifier.wosWOS:000262738500028
dc.language.isoenen_US
dc.publisherWiley-VCH Verlag GmbHen_US
dc.relation.ispartofZeitschrift für Anorganische und Allgemeine Chemieen_US
dc.relation.journalZeitschrift Fur Anorganische Und Allgemeine Chemieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyano-Bridged Complexen_US
dc.subjectTetracyanonickelate Complexen_US
dc.subjectTriethylenetetramine Complexen_US
dc.titleSynthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano-Bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ-CN)2(CN)2]nen_US
dc.typeArticleen_US
dspace.entity.typePublication

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