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Synthesis, Crystal Structure, Spectral and Thermal Studies of a New Organic-Inorganic Hybrid Cobalt(II) Complex of 2,2’-Bipyridine and Nitrate with Squarate

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dc.authorscopusid16403949600
dc.authorscopusid6603689883
dc.authorscopusid8205282600
dc.authorscopusid6603711357
dc.authorscopusid36039473500
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorPaşaoĝlu, H.
dc.contributor.authorKaştaş, G.
dc.contributor.authorÖlmez, H.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:25:34Z
dc.date.available2020-06-21T15:25:34Z
dc.date.issued2006
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Paşaoĝlu] Hümeyra, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Kaştaş] Gökhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Ölmez] Halis, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe [Co(NO<inf>3</inf>)(bipy)<inf>2</inf>](sq)<inf>1/2</inf> · 4H<inf>2</inf>O complex (I) (bipy: 2,2′-bipyridine, sq2-: squarate) has been prepared and characterized by elemental analysis, IR, UV/vis spectra, thermal analysis, and single crystal X-ray diffraction. The title compound crystallizes in the triclinic system, space group P1, with a = 7.6302(9), b = 12.0426(15), c = 14.2271(14) Å, α = 107.252(9)°, β = 98.755(9)°, γ = 103.363(9)° and Z = 2. The Co(II) ion in its octahedral complex is chelated by the nitrogen atoms of the two 2,2′-bipyridine, and by two oxygen atoms of the nitrato group. The anionic squarate behaves as a counter ion. Thermal analysis has shown that the title compound decomposes in three stages over the range 20-1000°C on heating in a static air atmosphere. The final decomposition product is CoO. © 2006 Verlag der Zeitschrift für Naturforschung.en_US
dc.identifier.doi10.1515/znb-2006-1011
dc.identifier.endpage1253en_US
dc.identifier.issn0932-0776
dc.identifier.issn1865-7117
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-33750947695
dc.identifier.scopusqualityQ3
dc.identifier.startpage1249en_US
dc.identifier.urihttps://doi.org/10.1515/znb-2006-1011
dc.identifier.volume61en_US
dc.identifier.wosWOS:000242481200011
dc.identifier.wosqualityQ4
dc.language.isoenen_US
dc.publisherVerlag der Zeitschrift für Naturforschungen_US
dc.relation.ispartofZeitschrift Für Naturforschung Section B-A Journal of Chemical Sciencesen_US
dc.relation.journalZeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subject2,2′-Bipyridineen_US
dc.subjectSquarateen_US
dc.subjectThermal Decompositionen_US
dc.titleSynthesis, Crystal Structure, Spectral and Thermal Studies of a New Organic-Inorganic Hybrid Cobalt(II) Complex of 2,2’-Bipyridine and Nitrate with Squarateen_US
dc.typeArticleen_US
dspace.entity.typePublication

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