Crystal Structure and Hirshfeld Surface Analysis of (E)-2-(2,4,6-Trimethylbenzylidene)-3,4-Dihydronaphthalen-1(2 H)-one

Abstract

A novel chalcone, C<inf>20</inf> H<inf>20</inf> O, derived from benzylidenetetralone, was synthesized via Claissen-Schmidt condensation between tetralone and 2,4,6-trimethylbenzaldehyde. In the crystal, molecules are linked by C - H...O hydrogen bonds, producing R2<inf>2</inf> (20) and R 2 4 (12) ring motifs. In addition, weak C - H...π and π-stacking interactions are observed. The intermolecular interactions were investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing that the most important contributions for the crystal packing are from H...H (66.0%), H...C/ C...H (22.3%), H...O/O...H (9.3%), and C...C (2.4%) interactions. Shape-index plots show π-π stacking interactions and the curvedness plots show flat surface patches characteristic of planar stacking. © 2019 Baydere et al.