Mesoporous silica synthesized from natural local kaolin as an effective adsorbent for removing of Acid Red 337 and its application in the treatment of real industrial textile effluent

Abstract

This paper presents a synthesis of mesoporous silica (MS) from natural clay as a silica source using Pluronic L35 (EO11PO16EO11) as a structure-directing agent. The prepared material was characterized by XRD, X-ray fluorescence, thermogravimetric analysis, SEM, TEM, and N2 adsorption-desorption analyses. Then, mesoporous material was used for the removal of Acid Red 337 (AR337) from aqueous solution, and the treatment of real textile effluent. The effect of pH, contact time, weight of adsorbent, and initial concentration was studied in batch adsorption. The synthesized mesoporous material showed good discoloration efficiency with a 62% percentage. Experiment with real textile wastewater showed that 39%, 40%, and 31.5% of the color, TOC, and chemical oxygen demand respectively were eliminated by using 1 g of MS per liter of wastewater.