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Effect of immobilization on catalytic characteristics of saturated Pd-N-heterocyclic carbenes in Mizoroki-Heck reactions
(Elsevier Science Sa, 2006)
A saturated Pd-N-heterocyclic complex was immobilized on an amorphous silica. The complex itself is of very high thermal stability. However, TEM observations, hot filtration, reusability, and poisoning tests all revealed ...
Silver, palladium and rhodium complexes of acenaphthylene-anuilated N-heterocyclic carbene ligands: A comparative study
(Wiley-V C H Verlag Gmbh, 2006)
The newly prepared carbene precursor 1,3-dimesitylacenaphtho[1,2-d]imidazolinium chloride, (NHC-H)Cl, 3, could be readily converted into the NHC-silver(l) complex, 4, which is an efficient carbene transfer agent and has ...