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X-ray and spectroscopy studies of antisymbiotic effect O-coordination of the 4-methoxy benzoyl methylene triphenyl phosphorane ligand in palladium(II) complex
(Elsevier Science Sa, 2009)
Complex [Pd(C6H4CH2NH2-k(2)-C,N)(Py)(OC (MeO-4-C6H4)=CH-PPh3)]OTf (1) (OTf = CF3SO3) represents the example of an ylide O-bound to a Pd(II) center that is unusual for the classical soft metals. O-coordination of ylides and ...