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Crystal structure and DFT computational studies of (E)-2,4-di-tert-butyl-6-{[3-(trifluoromethyl)benzyl]-iminomethyl}phenol
(Int Union Crystallography, 2020)
The title compound, C23H28F3NO, is an ortho-hydroxy Schiff base compound, which adopts the enol-imine tautomeric form in the solid state. The molecular structure is not planar and the dihedral angle between the planes of ...
Nickel (II) complex [NiCl2(DMF)(2)L-2] bearing diaminobenzene and sulfonamide: Crystal structure and catalytic application in the reduction of nitrobenzenes
(Pergamon-Elsevier Science Ltd, 2020)
A new Bis[N-(2-aminophenyl)benzenesulfonamidej-di-chloro-Bis[O'-N,N-dimethyl-formamide]-nickel (II) complex [NiCl2(DMF)(2)L2] was synthesized in DMF solution in reflux media with NiCl2.2H(2)O and the pre-prepared ...
Well-defined PEPPSI-themed palladium-NHC complexes: synthesis, and catalytic application in the direct arylation of heteroarenes
(Wiley, 2020)
In this study, a series of benzimidazolium salts were synthesized as unsymmetrical N-heterocyclic carbene (NHC) precursors. Benzimidazolium salts were used for synthesis of the PEPPSI (pyridine enhanced precatalyst preparation ...
Palladium-carbene catalyzed direct arylation of five-membered heteroaromatics
(Elsevier, 2020)
Due to the industrial importance of bi(hetero)arenes, the synthesis of these compounds by homogeneous Pd-catalyzed direct arylation is an important research topic in modern organic chemistry. In this study, PEPPSI-type, ...
Cu(ii) salen and 1,2,4-triazole complexes from thiosemicarbazone: synthesis, physicochemical and structural properties and cytotoxic activities
(Royal Soc Chemistry, 2020)
A triazole complex of copper(ii) containing ethylenediamine as a coligand was synthesized using salicylaldehydethiosemicarbazone in the presence of CuCl2. Also, a dinuclear copper(ii) complex was synthesized using the same ...
New Chalcone Derivative: Synthesis, Characterization, Computational Studies and Antioxidant Activity
(Bentham Science Publ Ltd, 2020)
A new chalcone derivative, called as 1-(4-(benzylideneamino)phenyl)-3-(furan-2-yl)prop-2-en-1-one (I), was synthezised and characterized by spectral methods (infrared (IR) and proton and carbon-13 nuclear magnetic resonance ...
Synthesis, DFT computations and antimicrobial activity of a Schiff base derived from 2-hydroxynaphthaldehyde: Remarkable solvent effect
(Elsevier, 2020)
A new Schiff base bearing sulfonamide group was synthesized and characterized by spectroscopic techniques. Its spectroscopic properties were investigated through density functional theory (DFT/B3LYP) method with the ...
Photoresponsivity and photodetectivity properties of copper complex-based photodiode
(Elsevier, 2020)
Spin coated Cu(II) complex thin layer onto p-Si substrate was used in photodiode fabrication. The structural properties of novel synthesized Cu(II) complex were investigated using different techniques. The single crystal ...
A neutral arene ruthenium(II) complex with a sulfonated N,O-chelating ligand: Synthesis, characterization, in vitro cytotoxicity and antibacterial activity
(Pergamon-Elsevier Science Ltd, 2020)
In this work, a new N,O-type ligand (L1H) containing a sulfonate ester group and its heteroleptic Ru(II) complex (C1) have been prepared and structurally characterized by various techniques, such as UV-vis, ESI-MS, NMR and ...
N-heterocyclic carbene palladium complexes with different N-coordinated ligands: Comparison of their catalytic activities in Suzuki-Miyaura and Mizoroki-Heck reactions
(Pergamon-Elsevier Science Ltd, 2020)
In this paper, we have reported the synthesis and catalytic activities of four new anthracene substituted imidazole-based palladium N-heterocyclic carbene complexes. The synthesized complexes, 2a-d, were stabilized with ...
