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Electrochemistry and structural properties of new mixed ligand nickel(II) complexes based on thiosemicarbazone
(Royal Soc Chemistry, 2014)
Mixed ligand nickel(II) complexes of 5-chloro-2-hydroxybenzophenone-N-R-thiosemicarbazone (R: -CH3 (L-1), -CH2-CH=CH2 (L-II)) and triphenylphosphine were synthesized. The structures of the complexes were characterized by ...
Supramolecular nickel complex based on thiosemicarbazone. Synthesis, transfer hydrogenation and unexpected thermal behavior
(Pergamon-Elsevier Science Ltd, 2016)
The cationic thiosemicarbazone complex of nickel containing triphenylphosphine as coligand was synthesized through the isopropanol-assisted hydrogen transfer reaction. The thiosemicarbazone ligand (LH2) and its cationic ...
Divalent nickel complexes of thiosemicarbazone based on 5-bromosalicylaldehyde and triphenylphosphine: Experimental and theoretical characterization
(Pergamon-Elsevier Science Ltd, 2016)
Two nickel(II) complexes containing 5-bromosalicylidene-N-methyl-S-methyl-isothiosemicarbazone (H(2)SMeNMeTsc) and 5-bromosalicylidene-N-methyl-thiosemicarbazone (H(2)NMeTsc) with triphenylphosphine were synthesized. The ...
Spectroscopic, electrochemical and X-ray diffraction studies on nickel(II)-complexes of acetophenone thiosemicarbazones substituted six-carbon groups
(Elsevier Science Sa, 2016)
Reactions of [Ni(PPh3)(2)Cl-2] with 3-Bromo-5-chloro-2-hydroxyacetophenone-N-4-hexyl ((LH2)-H-1), cyclohexyl (L2H2) and phenyl ((LH2)-H-3)-thiosemicarbazones resulted in four coordinated (ONSP) nickel(II) complexes, ...
Quantum-chemical, spectroscopic and X-ray diffraction studies on nickel complex of 2-hydroxyacetophenone thiosemicarbazone with triphenylphospine
(Pergamon-Elsevier Science Ltd, 2010)
Reaction of 2-hydroxyacetophenone thiosemicarbazone with [Ni(PPh(3))(2)Cl(2)] in optimized conditions afforded a mixed ligand complex with an isolated triphenylphosphine molecule. The structure was characterized by elemental ...
