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Iron(III) and nickel(II) complexes as potential anticancer agents: synthesis, physicochemical and structural properties, cytotoxic activity and DNA interactions
(Royal Soc Chemistry, 2015)
Template reactions of 2-hydroxy-R-benzaldehyde-S-methylisothiosemicarbazones (R = 3-methoxy or 4-hydroxy) with the corresponding aldehydes in the presence of FeCl3 and NiCl2 yielded N-1, N-4-disalicylidene chelate complexes. ...
Electrochemistry and structural properties of new mixed ligand nickel(II) complexes based on thiosemicarbazone
(Royal Soc Chemistry, 2014)
Mixed ligand nickel(II) complexes of 5-chloro-2-hydroxybenzophenone-N-R-thiosemicarbazone (R: -CH3 (L-1), -CH2-CH=CH2 (L-II)) and triphenylphosphine were synthesized. The structures of the complexes were characterized by ...
Dioxouranium(VI) complexes with N2O2 chelating thiosemicarbazones [UO2L(R-OH)]
(Taylor & Francis Ltd, 2013)
Three alkylated thiosemicarbazones (1-3) substituted on sulfur were synthesized using 5-bromosalicylaldehyde as starting material. The template reactions of the S-alkyl-thiosemicarbazones in the presence of dioxouranium(VI) ...
Supramolecular nickel complex based on thiosemicarbazone. Synthesis, transfer hydrogenation and unexpected thermal behavior
(Pergamon-Elsevier Science Ltd, 2016)
The cationic thiosemicarbazone complex of nickel containing triphenylphosphine as coligand was synthesized through the isopropanol-assisted hydrogen transfer reaction. The thiosemicarbazone ligand (LH2) and its cationic ...
Divalent nickel complexes of thiosemicarbazone based on 5-bromosalicylaldehyde and triphenylphosphine: Experimental and theoretical characterization
(Pergamon-Elsevier Science Ltd, 2016)
Two nickel(II) complexes containing 5-bromosalicylidene-N-methyl-S-methyl-isothiosemicarbazone (H(2)SMeNMeTsc) and 5-bromosalicylidene-N-methyl-thiosemicarbazone (H(2)NMeTsc) with triphenylphosphine were synthesized. The ...
Spectroscopic, electrochemical and X-ray diffraction studies on nickel(II)-complexes of acetophenone thiosemicarbazones substituted six-carbon groups
(Elsevier Science Sa, 2016)
Reactions of [Ni(PPh3)(2)Cl-2] with 3-Bromo-5-chloro-2-hydroxyacetophenone-N-4-hexyl ((LH2)-H-1), cyclohexyl (L2H2) and phenyl ((LH2)-H-3)-thiosemicarbazones resulted in four coordinated (ONSP) nickel(II) complexes, ...
Structural and spectroscopic characterization of a thiosemicarbazidatodioxouranium(VI) complex: A combined experimental and DFT study
(Pergamon-Elsevier Science Ltd, 2015)
The title thiosemicarbazidatodioxouranium(VI) compound was synthesized and characterized by FT-IR, NMR and UV-vis spectroscopies. Solid state structure of the compound was confirmed by X-ray crystallography. Besides, the ...
The asymmetric ONNO complexes of dioxouranium(VI) with N-1,N-4-diarylidene-S-propyl-thiosemicarbazones derived from 3,5-dichlorosalicylaldehyde: Synthesis, spectroscopic and structural studies
(Pergamon-Elsevier Science Ltd, 2011)
Two uranyl complexes having the composition [UO2(L)DMSO] were synthesized using salicyl- and 3,5-dichlorosalicylaldehyde-S-propyl-thiosemicarbazones as starting materials. The S-propyl-thiosemicarbazidato structures in the ...
Synthesis, X-ray crystal structures, thermal and electrochemical properties of thiosemicarbazidatodioxouranium(VI) complexes
(Royal Soc Chemistry, 2010)
The stable uranyl complexes, [UO2(L)C9H19OH], were obtained from 3,5-dichlorosalicyl-(L-I) and salicyl-aldehyde-S-propyl-thiosemicarbazones (L-II) with substituted-salicylaldehyde in nonyl alcohol. The structures of the ...
