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Supramolecular nickel complex based on thiosemicarbazone. Synthesis, transfer hydrogenation and unexpected thermal behavior
(Pergamon-Elsevier Science Ltd, 2016)
The cationic thiosemicarbazone complex of nickel containing triphenylphosphine as coligand was synthesized through the isopropanol-assisted hydrogen transfer reaction. The thiosemicarbazone ligand (LH2) and its cationic ...
Divalent nickel complexes of thiosemicarbazone based on 5-bromosalicylaldehyde and triphenylphosphine: Experimental and theoretical characterization
(Pergamon-Elsevier Science Ltd, 2016)
Two nickel(II) complexes containing 5-bromosalicylidene-N-methyl-S-methyl-isothiosemicarbazone (H(2)SMeNMeTsc) and 5-bromosalicylidene-N-methyl-thiosemicarbazone (H(2)NMeTsc) with triphenylphosphine were synthesized. The ...
Spectroscopic, electrochemical and X-ray diffraction studies on nickel(II)-complexes of acetophenone thiosemicarbazones substituted six-carbon groups
(Elsevier Science Sa, 2016)
Reactions of [Ni(PPh3)(2)Cl-2] with 3-Bromo-5-chloro-2-hydroxyacetophenone-N-4-hexyl ((LH2)-H-1), cyclohexyl (L2H2) and phenyl ((LH2)-H-3)-thiosemicarbazones resulted in four coordinated (ONSP) nickel(II) complexes, ...
