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Synthesis, Spectroscopic, Structural and Quantum Chemical Studies of a New Imine Oxime and Its Palladium(II) Complex: Hydrolysis Mechanism
(Mdpi, 2016)
In this work, we report synthesis, crystallographic, spectroscopic and quantum chemical studies of a new imine oxime, namely (4-nitro-phenyl)-(1-phenyl-ethylimino)-acetaldehyde oxime (nppeieoH). Spectroscopic and X-ray ...
Synthesis, structures and biomolecular interactions of new silver(I) 5,5-diethylbarbiturate complexes of monophosphines targeting Gram-positive bacteria and breast cancer cells
(Royal Soc Chemistry, 2017)
A series of new silver(I) 5,5-diethylbarbiturate (barb) complexes with the formulas [Ag-2(mu-barb)(2)(PPh3)(2)] (1), [Ag(barb)(PPh2Cy)] (2), [Ag(barb)(PPhCy2)] (3) and [Ag(barb)(PCy3)] (4) (PPh3 = triphenylphosphine, PPh2Cy ...
Palladium(II) and platinum(II) complexes of a new imineoxime ligand - Structural, spectroscopic and DFT/time-dependent (TD) DFT studies
(Elsevier Science Sa, 2014)
A new imineoxime compound, (1E, 2E)-[(2-hydroxyethyl) imino]-2-phenyl-ethanal oxime (heipeoH) and its palladium(II) and platinum(II) complexes ([M(heipeo)(2)]) have been synthesized and characterized by elemental analysis, ...
Synthesis, crystal structures, in vitro DNA binding, antibacterial and cytotoxic activities of new di- and polynuclear silver(I) saccharinate complexes with tertiary monophosphanes
(Elsevier Science Sa, 2014)
Four new silver(I) saccharinate (sac) complexes, [Ag(mu-sac)(PPh3)](2) (1), [Ag(mu-sac)(PPh2CY)](2) (2), [Ag(mu-sac)(PPhCy2)](2) (3) and [Ag(mu-sac)(PCy3)](n) (4), where PPh3 = triphenylphosphane, PPh2Cy = cyclohexyldiph ...
Synthesis, structural characterization and cell death-inducing effect of novel palladium(II) and platinum(II) saccharinate complexes with 2-(hydroxymethyl)pyridine and 2-(2-hydroxyethyl) pyridine on cancer cells in vitro
(Pergamon-Elsevier Science Ltd, 2013)
Four palladium(II) and platinum(II) saccharinate (sac) complexes with 2-(hydroxymethyl) pyridine (2-hmpy) and 2-(2-hydroxyethyl) pyridine (2-hepy), namely trans-[Pd(2-hmpy)(2)(sac)(2)]center dot H2O (1), trans-[Pt(2-hmpy ...
Di- and polynuclear silver(I) saccharinate complexes of tertiary diphosphane ligands: synthesis, structures, in vitro DNA binding, and antibacterial and anticancer properties
(Springer, 2014)
A series of new silver(I) saccharinate (sac) complexes, [Ag-2(sac)(2)(mu-dppm)H2O]center dot H2O (1), {[Ag-2(mu-sac)(2)(mu-dppe)]center dot 3H(2)O center dot CH2Cl2} (n) (2), [Ag-2(mu-sac)(2)(mu-dppp)] (n) (3), and ...
Synthesis, characterization and structures of solvent-mediated Na(I)-Pd(II) heterometallic complexes containing [Pd(barb)(4)](2-) units (barb=5,5-diethylbarbiturate)
(Taylor & Francis Ltd, 2016)
Reaction of Na-2[PdCl4] with the sodium salt of 5,5-diethylbarbituric acid (barbH) led to the formation of two complexes, [PdNa2(-barb)(4)(DMSO)(2)]2H(2)ODMSO (1), and {[PdNa2(-barb)(4)(H2O)]3H(2)O}(n) (2). The complexes ...
Cationic Pd(II)/Pt(II) 5,5-diethylbarbiturate complexes with bis(2-pyridylmethyl)amine and terpyridine: Synthesis, structures,DNA/BSA interactions, intracellular distribution, cytotoxic activity and induction of apoptosis
(Elsevier Science Inc, 2015)
Four new cationic Pd(II) and Pt(II) 5,5-diethylbarbiturate (barb) complexes, [M(barb)(bpma)]X center dot H2O [M = pd(II), X = Cl (1); M = Pt-II, X = NO3- (2)] and [M(barb)(terPY)]NO3 center dot 0.5H(2)O [M = Pd-II (3); M ...
Structural, spectroscopic and quantum chemical studies of acetyl hydrazone oxime and its palladium(II) and platinum(II) complexes
(Elsevier Science Bv, 2015)
Acetyl hydrazone oxime, [(1E,26)-2-(hydroxyimino)-1-phenylethylidene]acetohydrazone (hipeahH(2)) and its palladium(II) and platinum(II) complexes, [M(hipeahH)(2)] (M = Pd-II and Pt-II), have been synthesized and characterized ...
A palladium(II) complex containing both carbonyl and imine oxime ligands: Crystal structure, experimental and theoretical UV-vis, IR and NMR studies
(Pergamon-Elsevier Science Ltd, 2013)
A new palladium(II) complex, [Pd(ppeieo)(inap)]center dot DMSO (ppeieo = (1E,2E)-phenyl-[(1-phenylethyl)imino]-ethanal oxime and imp = isonitrosoacetophenone) has been synthesized and characterized by elemental analysis, ...
