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Iron(III) and nickel(II) complexes as potential anticancer agents: synthesis, physicochemical and structural properties, cytotoxic activity and DNA interactions
(Royal Soc Chemistry, 2015)
Template reactions of 2-hydroxy-R-benzaldehyde-S-methylisothiosemicarbazones (R = 3-methoxy or 4-hydroxy) with the corresponding aldehydes in the presence of FeCl3 and NiCl2 yielded N-1, N-4-disalicylidene chelate complexes. ...
Cu(ii) salen and 1,2,4-triazole complexes from thiosemicarbazone: synthesis, physicochemical and structural properties and cytotoxic activities
(Royal Soc Chemistry, 2020)
A triazole complex of copper(ii) containing ethylenediamine as a coligand was synthesized using salicylaldehydethiosemicarbazone in the presence of CuCl2. Also, a dinuclear copper(ii) complex was synthesized using the same ...
Electrochemistry and structural properties of new mixed ligand nickel(II) complexes based on thiosemicarbazone
(Royal Soc Chemistry, 2014)
Mixed ligand nickel(II) complexes of 5-chloro-2-hydroxybenzophenone-N-R-thiosemicarbazone (R: -CH3 (L-1), -CH2-CH=CH2 (L-II)) and triphenylphosphine were synthesized. The structures of the complexes were characterized by ...
Dioxouranium(VI) complexes with N2O2 chelating thiosemicarbazones [UO2L(R-OH)]
(Taylor & Francis Ltd, 2013)
Three alkylated thiosemicarbazones (1-3) substituted on sulfur were synthesized using 5-bromosalicylaldehyde as starting material. The template reactions of the S-alkyl-thiosemicarbazones in the presence of dioxouranium(VI) ...
Supramolecular nickel complex based on thiosemicarbazone. Synthesis, transfer hydrogenation and unexpected thermal behavior
(Pergamon-Elsevier Science Ltd, 2016)
The cationic thiosemicarbazone complex of nickel containing triphenylphosphine as coligand was synthesized through the isopropanol-assisted hydrogen transfer reaction. The thiosemicarbazone ligand (LH2) and its cationic ...
Divalent nickel complexes of thiosemicarbazone based on 5-bromosalicylaldehyde and triphenylphosphine: Experimental and theoretical characterization
(Pergamon-Elsevier Science Ltd, 2016)
Two nickel(II) complexes containing 5-bromosalicylidene-N-methyl-S-methyl-isothiosemicarbazone (H(2)SMeNMeTsc) and 5-bromosalicylidene-N-methyl-thiosemicarbazone (H(2)NMeTsc) with triphenylphosphine were synthesized. The ...
Spectroscopic, electrochemical and X-ray diffraction studies on nickel(II)-complexes of acetophenone thiosemicarbazones substituted six-carbon groups
(Elsevier Science Sa, 2016)
Reactions of [Ni(PPh3)(2)Cl-2] with 3-Bromo-5-chloro-2-hydroxyacetophenone-N-4-hexyl ((LH2)-H-1), cyclohexyl (L2H2) and phenyl ((LH2)-H-3)-thiosemicarbazones resulted in four coordinated (ONSP) nickel(II) complexes, ...
Structural and spectroscopic characterization of a thiosemicarbazidatodioxouranium(VI) complex: A combined experimental and DFT study
(Pergamon-Elsevier Science Ltd, 2015)
The title thiosemicarbazidatodioxouranium(VI) compound was synthesized and characterized by FT-IR, NMR and UV-vis spectroscopies. Solid state structure of the compound was confirmed by X-ray crystallography. Besides, the ...
The asymmetric ONNO complexes of dioxouranium(VI) with N-1,N-4-diarylidene-S-propyl-thiosemicarbazones derived from 3,5-dichlorosalicylaldehyde: Synthesis, spectroscopic and structural studies
(Pergamon-Elsevier Science Ltd, 2011)
Two uranyl complexes having the composition [UO2(L)DMSO] were synthesized using salicyl- and 3,5-dichlorosalicylaldehyde-S-propyl-thiosemicarbazones as starting materials. The S-propyl-thiosemicarbazidato structures in the ...
Synthesis, X-ray crystal structures, thermal and electrochemical properties of thiosemicarbazidatodioxouranium(VI) complexes
(Royal Soc Chemistry, 2010)
The stable uranyl complexes, [UO2(L)C9H19OH], were obtained from 3,5-dichlorosalicyl-(L-I) and salicyl-aldehyde-S-propyl-thiosemicarbazones (L-II) with substituted-salicylaldehyde in nonyl alcohol. The structures of the ...
