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Toplam kayıt 11, listelenen: 1-10
(2Z,6Z)-N-2,N-2 '-bis(2,6-diisopropylphenyl)-N-1,N-1 '-bis(2-methoxyethyl)pyridine-2,6-dicarboxamidine
(Blackwell Publishing, 2008)
In the title compound, C37H53N5O2, the benzene rings make dihedral angles of 84.61 (8) and 67.10 (9)degrees with the pyridine ring. The crystal structure is stabilized by strong intramolecular interactions. The two ...
The influence of moisture on deprotonation mode of imidazolinium chlorides with palladacycle acetate dimer
(Elsevier Science Sa, 2009)
Deprotonation of 1,3-diorganyl imidazolinium salts, 1, with N,C-type palladacyclic acetate dimer 2 afforded novel NHC coordinated complexes 3 along with ring opening hydrolysis products 4, which may coordinate to palladium ...
New (kappa(2)-C,N)-palladacyclic complexes with benzimidazol-2-ylidene ligand: Synthesis, crystal structures and characterization
(Elsevier Science Bv, 2009)
Reaction of unsymmetrical benzimidazolium bromides (1) with Ag2O and subsequent transmetallation with chloro-bridged dinuclear palladacycle, [Pd(dmba)(mu-Cl](2) (dmba: N,N-dimethylbenzylamine) afforded benzannulated ...
Synthesis, X-ray structures, and catalytic activities of (kappa(2)-C,N)-palladacycles bearing imidazol-2-ylidenes
(Elsevier Science Sa, 2009)
Quaternisation of methylimidazole (1) by methyl substituted benzyl bromides afforded imidazolium salts (2) which were converted to (kappa(2)-C, N)-palladacycles bearing imidazol-2-ylidenes 6 or 7, by either in situ ...
(Acetonitrile){2,6-bis[1-(2-ethyl-6-methylphenylimino)ethyl]pyridine} dichlororuthenium(II) dichloromethane hemisolvate: a chain of edge-fused R-6(6)(24) rings
(Blackwell Publishing, 2007)
In the title compound, [RuCl2(C2H3N)(C27H31N3)] (.) 0.5CH(2)-Cl-2, the Ru-II ion is six-coordinated in a distorted octahedral arrangement, with the two Cl atoms located in the apical positions, and the pyridine (py) N atom, ...
(2,6-bis{1-[4-(dimethylamino)phenylimino]ethyl}pyridine)dichlorido(tri-phenylphosphine-kappa P)ruthenium(II): a zigzag chain of fused centrosymmetric R-2(2)(12) rings
(Int Union Crystallography, 2007)
The title compound, [RuCl2(C25H29N5)(C18H15P)], a transfer hydrogenation catalyst, is supported by an N,N',N"-tridentate pyridine-bridged ligand and triphenylphosphine. The Run centre is six-coordinated in a distorted ...
A mu-chloro-bridged dinuclear ruthenium complex with 9H-carbazole: the formation of one-dimensional linear chains of star-shaped edge-fused rings
(Blackwell Publishing, 2006)
The title complex, di-mu-chloro-bis[chloro(eta(6)-p-cymene)ruthenium(II)]-9H-carbazole (1/2), [Ru2Cl4(C10H14)(2)](.)2C(12)H(9)N, is composed of one [RuCl2(eta(6)-p-cymene)](2) and two 9H-carbazole molecules. There are ...
Dichloro[(1E,1'E)-1,1'-(pyridine-2,6-diyl)diethanone bis(O-methyloxime)-k(3)N(1),N-2,N-6]cobalt(II)
(Int Union Crystallography, 2006)
In the title compound, [CoCl2(C11H15N3O2)], the Co-II ion is five-coordinated in a strongly distorted square-pyramidal arrangement, with one of the two Cl atoms located in the apical position, and the other Cl atom and the ...
Dichloro[(1E,1 ' E)-1,1 '-(pyridine-2,6-diyl)diethanone bis (O-methyloxime)-kappa(3) N-1, N-2, N-6] copper(II)
(Blackwell Publishing, 2006)
In the title compound, [CuCl2(C11H15N3O2)], the Cu-II ion is five-coordinated in a strongly distorted trigonal-bipyramidal arrangement, with the two methyloxime N atoms located in the apical positions, and the pyridine N ...
Brorno(eta(4)-cycloocta-1,5-diene)[1-(2,3,4,5,6-pentafluorobenzyl)-3-(2, 4,6-trimethylbenzyl benzimidazol-2-ylidenel rhodium(I)
(Int Union Crystallography, 2006)
The title complex, [RhBr(C8H12)(C24H19F5N2)], has a distorted pseudo-square- planar geometry. The Rh-C bond distance between the N-heterocyclic ligand and the metal atom is 2.022 (3) angstrom. The angle between the carbene ...