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Supramolecular nickel complex based on thiosemicarbazone. Synthesis, transfer hydrogenation and unexpected thermal behavior

Guveli, Sukriye; Bal-Demirci, Tulay; Ulkuseven, Bahri; Özdemir, Namık (Pergamon-Elsevier Science Ltd, 2016)

The cationic thiosemicarbazone complex of nickel containing triphenylphosphine as coligand was synthesized through the isopropanol-assisted hydrogen transfer reaction. The thiosemicarbazone ligand (LH2) and its cationic ...