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Synthesis, Structural, and Spectroscopic (FT-IR, NMR, and UV) Characterization of 1-(Cyclohexylmethyl)-2-(pyridin-2-yl)-1H-benzo[d]imidazole by Experimental Techniques and Quantum Chemical Calculations
(Pleiades Publishing Inc, 2016)
The title compound (II), 1-(cyclohexylmethyl)-2-(pyridin-2-yl)-1H-benzo[d]imidazole (C19H21N3), was synthesized via N-alkylation of 2-(pyridin-2-yl)-1H-benzo[d] imidazole (I). Both compounds I and II were characterized by ...
Investigation of enol-imine/keto-amine tautomerism in (E)-4-[(2-hydroxybenzylidene)amino]phenyl benzenesulphonate by experimental and molecular modelling methods
(Taylor & Francis Ltd, 2016)
The Schiff base compound (E)-4-[(2-hydroxybenzylidene)amino]phenyl benzenesulphonate has been synthesised from the reaction of 4-aminophenyl benzenesulphonate and salicylaldehyde, and characterised by spectroscopic and ...
A new phosphazene derivative, spiro-N3P3[(O2C12H8)(2)(OC6H6N-3)(2)], and its Ru(II) complex: Syntheses, crystal structure, catalytic activity and antimicrobial activity studies
(Pergamon-Elsevier Science Ltd, 2015)
A cyclotriphosphazene ligand containing the spirocyclic 2,2'-dioxybiphenyl group and 2-methy1-3-pyridyloxy moieties was synthesized. A Ru(11) complex was prepared from the reaction of [RuCl2(p-cymene)](2) with this ligand. ...
Synthesis, spectroscopic characterization, X-ray structure and DFT studies on 2,6-bis(1-benzyl-1H-benzo[d]imidazol-2-yl)pyridine
(Pergamon-Elsevier Science Ltd, 2013)
The title molecule, 2,6-bis(1-benzyl-1H-benzo[d]imidazol-2-yl)pyridine (C33H25N5), was synthesized and characterized by elemental analysis, FT-IR spectroscopy, one- and two-dimensional NMR spectroscopies, and single-crystal ...
Experimental and molecular modeling investigation of (E)-N-{2-[(2-hydroxybenzylidene)amino]phenyl}benzenesulfonamide
(Taylor & Francis Ltd, 2013)
The Schiff base compound (E)-N-{2-[(2-hydroxybenzylidene)amino]phenyl}benzenesulfonamide has been synthesized and characterized by IR, NMR and Uv-vis spectroscopies, and single-crystal X-ray diffraction technique. In ...
Synthesis and characterization of SiO2-supported ruthenium complexes containing aromatic sulfonamides: as catalysts for transfer hydrogenation of acetophenone
(Royal Soc Chemistry, 2013)
3-Amino-N-aryl-benzenesulfonamides (1-3) were successfully synthesized by the reaction of m-phenylenediamine and various benzenesulfonyl chlorides. Then, a series of ruthenium complexes (4-6) were prepared from the reaction ...
Synthesis and catalytic activity of ruthenium(II) complexes containing pyridine-based tridentate triamines ('NNN') and pyridine carboxylate ligands (NO)
(Elsevier Science Sa, 2012)
The reaction of [(p-cymene)RuCl2](2) with K[NOa-b] (NO- = 2-picolinate, a or 2-quinaldinate, b) gave neutral [(p-cymene)RuCl(NOa-b)] (1a-b), complexes which were treated with pyridine-based meridional triamine ligands ...
Synthesis and characterization of 2,2 '-(pyridine-2,6-diyl)bis (1H-benzo[d]imidazol-3-ium) 2,4,6-trimethylbenzenesulfonate chloride by experimental and theoretical methods
(Pergamon-Elsevier Science Ltd, 2014)
The title molecular salt (2), 2,2 '-(pyridine-2,6-diyl)bis (1H-benzo[d]imidazol-3-ium) 2,4,6-trimethylbenzenesulfonate chloride (C19H15N52+center dot C9H11O3S-.Cl-), was synthesized unexpectedly from the reaction of ...
Direct and solvent-assisted thione-thiol tautomerism in 5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thione: Experimental and molecular modeling study
(Elsevier, 2014)
The compound has been synthesized and characterized by IR, NMR and X-ray diffraction. Quantum chemical calculations at B3LYP/6-311++G(d,p) level were performed to study the molecular and spectroscopic properties, conformational ...
Synthesis of some ruthenium(II)-Schiff base complexes bearing sulfonamide fragment: New catalysts for transfer hydrogenation of ketones
(Elsevier Science Sa, 2014)
Four new ruthenium(II) complexes [RuCl(1-4)(p-cymene)] (1-4 = N-(3-(2-hydroxybenzylideneamino)phenyl) benzenesulfonamides) were synthesized from [RuCl2(p-cymene)](2) with Schiff base ligands containing aromatic sulfonamide ...
