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Synthesis, Spectroscopic, Structural and Quantum Chemical Studies of a New Imine Oxime and Its Palladium(II) Complex: Hydrolysis Mechanism
(Mdpi, 2016)
In this work, we report synthesis, crystallographic, spectroscopic and quantum chemical studies of a new imine oxime, namely (4-nitro-phenyl)-(1-phenyl-ethylimino)-acetaldehyde oxime (nppeieoH). Spectroscopic and X-ray ...
(3-Hydroxy-2-pyridylmethyl)dimethylammonium dihydrogen phosphate
(Int Union Crystallography, 2006)
The title compound, C8H13N2O+center dot H2PO4-, is an ionic salt. The organic species is protonated at the N atom of the dimethylaminomethyl group. The dihydrogenphosphate moieties are connected into infinite chains by way ...
A second polymorph of 2-aminopyridinium dihydrogenphosphate
(Int Union Crystallography, 2005)
In the title compound, beta-C5H7N2+center dot H2PO4-, the tetrahedral dihydrogenphosphate moieties are linked into double chains by O-H center dot center dot center dot O hydrogen bonds, and the organic species crosslink ...
trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)
(Wiley-Blackwell, 2008)
In the centrosymmetric title complex, [Co(C7H4NO3S)(2)(C6H15N3)(2)], the Co-II ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral ...
Synthesis, structures and biomolecular interactions of new silver(I) 5,5-diethylbarbiturate complexes of monophosphines targeting Gram-positive bacteria and breast cancer cells
(Royal Soc Chemistry, 2017)
A series of new silver(I) 5,5-diethylbarbiturate (barb) complexes with the formulas [Ag-2(mu-barb)(2)(PPh3)(2)] (1), [Ag(barb)(PPh2Cy)] (2), [Ag(barb)(PPhCy2)] (3) and [Ag(barb)(PCy3)] (4) (PPh3 = triphenylphosphine, PPh2Cy ...
Palladium(II) and platinum(II) complexes of a new imineoxime ligand - Structural, spectroscopic and DFT/time-dependent (TD) DFT studies
(Elsevier Science Sa, 2014)
A new imineoxime compound, (1E, 2E)-[(2-hydroxyethyl) imino]-2-phenyl-ethanal oxime (heipeoH) and its palladium(II) and platinum(II) complexes ([M(heipeo)(2)]) have been synthesized and characterized by elemental analysis, ...
Synthesis, crystal structures, in vitro DNA binding, antibacterial and cytotoxic activities of new di- and polynuclear silver(I) saccharinate complexes with tertiary monophosphanes
(Elsevier Science Sa, 2014)
Four new silver(I) saccharinate (sac) complexes, [Ag(mu-sac)(PPh3)](2) (1), [Ag(mu-sac)(PPh2CY)](2) (2), [Ag(mu-sac)(PPhCy2)](2) (3) and [Ag(mu-sac)(PCy3)](n) (4), where PPh3 = triphenylphosphane, PPh2Cy = cyclohexyldiph ...
Synthesis, structural characterization and cell death-inducing effect of novel palladium(II) and platinum(II) saccharinate complexes with 2-(hydroxymethyl)pyridine and 2-(2-hydroxyethyl) pyridine on cancer cells in vitro
(Pergamon-Elsevier Science Ltd, 2013)
Four palladium(II) and platinum(II) saccharinate (sac) complexes with 2-(hydroxymethyl) pyridine (2-hmpy) and 2-(2-hydroxyethyl) pyridine (2-hepy), namely trans-[Pd(2-hmpy)(2)(sac)(2)]center dot H2O (1), trans-[Pt(2-hmpy ...
Di- and polynuclear silver(I) saccharinate complexes of tertiary diphosphane ligands: synthesis, structures, in vitro DNA binding, and antibacterial and anticancer properties
(Springer, 2014)
A series of new silver(I) saccharinate (sac) complexes, [Ag-2(sac)(2)(mu-dppm)H2O]center dot H2O (1), {[Ag-2(mu-sac)(2)(mu-dppe)]center dot 3H(2)O center dot CH2Cl2} (n) (2), [Ag-2(mu-sac)(2)(mu-dppp)] (n) (3), and ...
Synthesis, characterization and structures of solvent-mediated Na(I)-Pd(II) heterometallic complexes containing [Pd(barb)(4)](2-) units (barb=5,5-diethylbarbiturate)
(Taylor & Francis Ltd, 2016)
Reaction of Na-2[PdCl4] with the sodium salt of 5,5-diethylbarbituric acid (barbH) led to the formation of two complexes, [PdNa2(-barb)(4)(DMSO)(2)]2H(2)ODMSO (1), and {[PdNa2(-barb)(4)(H2O)]3H(2)O}(n) (2). The complexes ...
