Browsing by Author "Karami, Kazem"
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(4-Methoxybenzoylmethyl)triphenylphosphonium trifluoromethanesulfonate
Karami, Kazem; Büyükgüngör, Orhan (Int Union Crystallography, 2009)Colourless crystals of the title compound, C27H24O2P+center dot-CF3SO3-, have been prepared by the addition of a solution of AgCF3SO3 in methanol to a solution of (4-methoxy-benzoylmethyl) triphenylphosphonium bromide in ... -
Di-mu-iodido-bis{[(4-fluorobenzoylmethylene)triphenyl-lambda(5)-phosphorane]iodido-mercury(II)}
Akkurt, Mehmet; Karami, Kazem; Yalcin, Serife Pinar; Büyükgüngör, Orhan (Blackwell Publishing, 2008)In the title complex, [Hg2I4(C26H20FOP)(2)], the Hg-II centre is four-coordinate with one short Hg-I bond [2.6895 (7) A], one Hg-C bond and two asymmetric bridging Hg-I bonds with distances of 2.7780 (8) and 3.2599 (8) A. ... -
Mono- and binuclear orthopalladated complexes of phosphorus ylides containing nitrogen, phosphorus or bridging diphosphine ligands: Self-assembly, theoretical calculations and comparative catalytic activity
Karami, Kazem; Abedanzadeh, Sedigheh; Yadollahi, Firoozeh; Büyükgüngör, Orhan; Farrokhpour, Hossein; Rizzoli, Corrado; Lipkowski, Janusz (Elsevier Science Sa, 2015)Binuclear orthopalladated complexes of phosphorus ylides containing electron-withdrawing fluoro (Y1), bromo (Y2) or phenyl (Y3) substituent, [Pd{kappa(2)(C, C)-[(C6H4-2)PPh2] CH(CO) C6H4X-4}(m-Cl)](2) (X = F (1), Br (2), ... -
New phosphorus ylide palladacyclic: Synthesis, characterization, X-Ray crystal structure, biomolecular interaction studies, molecular docking and in vitro cytotoxicity evaluations
Karami, Kazem; Rahimi, Mahzad; Zakariazadeh, Mostafa; Büyükgüngör, Orhan; Amirghofran, Zahra (Elsevier Science Sa, 2018)The ylide-phosphonium salt [PPh3CH2C(O)CH2Cl]Cl-+(-) was reacted with Pd(OAc)(2) to give the chlorobridged dinuclear complex [Pd{C(H)PPh3C(O)CH2Cl}(mu-Cl)(OAc)](2), which experienced bridge cleavage reactions with ... -
A novel silver. (I) complex of alpha-keto phosphorus ylide: Synthesis, characterization, crystal structure, biomolecular interaction studies, molecular docking and in vitro cytotoxic evaluation
Karami, Kazem; Rahimi, Mahzad; Zakariazadeh, Mostafa; Büyükgüngör, Orhan; Momtazi-Borojeni, Amir Abbas; Esmaeili, Seyed-Alireza (Elsevier Science Bv, 2019){[Ag(FBPY)(2)](+)(FBPYH)(+)}(OTF)(2), FBPY=FPhC(O)C(H)PPh3, FBPYH =FC6H4COCH2PPh3, OTF=CF3SO3, a ylidic complex, was prepared through the reaction of silver trifluoromethanesulfonate (AgOTf) and ylide [FBPY] in 1:2 M ratio ...